{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T10:29:11Z","timestamp":1786616951851,"version":"build-2736575974"},"reference-count":44,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2026,7,14]],"date-time":"2026-07-14T00:00:00Z","timestamp":1783987200000},"content-version":"vor","delay-in-days":13,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T00:00:00Z","timestamp":1782864000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100003593","name":"Conselho Nacional de Desenvolvimento Cient\u00edfico e Tecnol\u00f3gico","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003593","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001807","name":"Funda\u00e7\u00e3o de Amparo \u00e0 Pesquisa do Estado de S\u00e3o Paulo","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001807","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["analyticalsciencejournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["J of Separation Science"],"published-print":{"date-parts":[[2026,7]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    This work presents a fast and straightforward chromatographic method with fluorescence detection to quantify glufosinate in soil solutions. The method is based on the reaction between the primary amine group of glufosinate and\n                    <jats:italic>o\u2010<\/jats:italic>\n                    phthaldialdehyde with 2\u2010mercaptoethanol, producing a stable fluorescent derivative in under 2 min, which remains stable for more than 70 min (relative standard deviation [RSD] = 3.6%). The method does not require automated timing systems. Glyphosate, which lacks a primary amine, does not interfere, and potential interferences from aminomethyl phosphonic acid and ammonium are effectively circumvented by chromatographic separation, as their indole derivatives are well resolved from the glufosinate derivative. An isocratic chromatographic run using 20:80 methanol:piperazine\u2010\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>N<\/jats:italic>\n                    \u2032\u2010bis(2\u2010ethanesulfonic acid) buffer at 1.0 mL\/min lasts 5 min. The method showed linearity over the concentration range of 0.10 and 20 \u00b5mol\/L, with detection and quantification limits of 0.015 and 0.050 \u00b5mol\/L, respectively. Calibration curve reproducibility is high (slope RSD &lt; 2.1%,\n                    <jats:italic>n<\/jats:italic>\n                    = 5). The method was effectively applied to study glufosinate adsorption in an Oxisol, revealing a maximum adsorption capacity of 2.5 \u00b1 0.2 \u00b5mol\/g, significantly lower than that reported for glyphosate.\n                  <\/jats:p>","DOI":"10.1002\/jssc.70491","type":"journal-article","created":{"date-parts":[[2026,7,14]],"date-time":"2026-07-14T13:12:39Z","timestamp":1784034759000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Quick and Simple Chromatographic Method to Investigate the Adsorption of Glufosinate on a Subtropical Oxisol: Affinity Comparisons With Glyphosate"],"prefix":"10.1002","volume":"49","author":[{"given":"Tatiana Valeria","family":"Furquim","sequence":"first","affiliation":[{"name":"Departamento de Qu\u00edmica Fundamental Instituto de Qu\u00edmica Universidade de S\u00e3o Paulo  S\u00e3o Paulo Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Luan","family":"Viana","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Fundamental Instituto de Qu\u00edmica Universidade de S\u00e3o Paulo  S\u00e3o Paulo Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0496-9009","authenticated-orcid":false,"given":"Jorge C.","family":"Masini","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Fundamental Instituto de Qu\u00edmica Universidade de S\u00e3o Paulo  S\u00e3o Paulo Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,14]]},"reference":[{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.1100\/2012\/657945"},{"key":"e_1_2_10_3_1","doi-asserted-by":"publisher","DOI":"10.1017\/wsc.2021.3"},{"key":"e_1_2_10_4_1","doi-asserted-by":"publisher","DOI":"10.51694\/AdvWeedSci\/2022;40:seventy\u2010five009"},{"key":"e_1_2_10_5_1","doi-asserted-by":"publisher","DOI":"10.1017\/wet.2022.79"},{"key":"e_1_2_10_6_1","doi-asserted-by":"publisher","DOI":"10.3390\/min11111282"},{"key":"e_1_2_10_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/ps.4172"},{"key":"e_1_2_10_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.microc.2015.02.007"},{"key":"e_1_2_10_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2022.463631"},{"key":"e_1_2_10_10_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00216\u2010008\u20102134\u20105"},{"key":"e_1_2_10_11_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10337\u2010019\u201003748\u20103"},{"key":"e_1_2_10_12_1","doi-asserted-by":"publisher","DOI":"10.1556\/AChrom.21.2009.4.4"},{"key":"e_1_2_10_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2022.130654"},{"key":"e_1_2_10_14_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00216\u2010016\u20109597\u20106"},{"key":"e_1_2_10_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2013.07.037"},{"key":"e_1_2_10_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2020.461226"},{"key":"e_1_2_10_17_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11356\u2010017\u20108522\u20107"},{"key":"e_1_2_10_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021\u20109673(97)01129\u20101"},{"key":"e_1_2_10_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.geoderma.2011.11.027"},{"key":"e_1_2_10_20_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00216\u2010019\u201001672\u2010x"},{"key":"e_1_2_10_21_1","doi-asserted-by":"publisher","DOI":"10.1080\/03601234.2019.1644947"},{"key":"e_1_2_10_22_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF02492091"},{"key":"e_1_2_10_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac50047a019"},{"key":"e_1_2_10_24_1","doi-asserted-by":"publisher","DOI":"10.1590\/01000683rbcs20140655"},{"key":"e_1_2_10_25_1","first-page":"1","article-title":"About the Theory of so\u2010called Adsorption of Soluble Substances. K. Sven. Vetensk","volume":"24","author":"Lagergren S.","year":"1898","journal-title":"Handl"},{"key":"e_1_2_10_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/0043\u20101354(84)90124\u20106"},{"key":"e_1_2_10_27_1","doi-asserted-by":"publisher","DOI":"10.1061\/JSEDAI.0000430"},{"key":"e_1_2_10_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja02242a004"},{"key":"e_1_2_10_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.watres.2017.04.014"},{"key":"e_1_2_10_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/i160018a011"},{"key":"e_1_2_10_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.heliyon.2023.e15128"},{"key":"e_1_2_10_32_1","doi-asserted-by":"publisher","DOI":"10.1080\/03601234.2023.2238591"},{"key":"e_1_2_10_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021\u20109673(00)01200\u20100"},{"key":"e_1_2_10_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021\u20109673(01)89596\u20100"},{"key":"e_1_2_10_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2008.08.030"},{"key":"e_1_2_10_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.200800741"},{"key":"e_1_2_10_37_1","unstructured":"Minnesota Department of Agriculture.Glufosinate Herbicide https:\/\/www.mda.state.mn.us\/glufosinate\u2010herbicide(Accessed: April 1 2025)."},{"key":"e_1_2_10_38_1","doi-asserted-by":"publisher","DOI":"10.20517\/mmm.2022.01"},{"key":"e_1_2_10_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-08-098259-5.00016-0"},{"key":"e_1_2_10_40_1","first-page":"1","article-title":"Ab Initio Molecular Dynamics Simulations of the Interaction Between Organic Phosphates and Goethite","volume":"26","author":"Ganta P. B.","year":"2021","journal-title":"Molecules"},{"key":"e_1_2_10_41_1","doi-asserted-by":"publisher","DOI":"10.1006\/jcis.2001.7994"},{"key":"e_1_2_10_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-443-14034-1.00009-5"},{"key":"e_1_2_10_43_1","first-page":"260","article-title":"Conceitos Fundamentais sobre Energia de Intera\u00e7\u00e3o a Partir de uma Revis\u00e3o Bibliogr\u00e1fica do Tema Intera\u00e7\u00f5es Intermoleculares","volume":"21","author":"Seribeli F. L.","year":"2022","journal-title":"Revista Electr\u00f3nica de Ense\u00f1anza de las Ciencias"},{"key":"e_1_2_10_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2016.03.239"},{"key":"e_1_2_10_45_1","first-page":"1","article-title":"Efficient Interatomic Descriptors for Accurate Machine Learning Force Fields of Extended Molecules","volume":"14","author":"Kabylda A.","year":"2023","journal-title":"Nature Communications"}],"container-title":["Journal of Separation Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/jssc.70491","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/jssc.70491","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/jssc.70491","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T09:41:51Z","timestamp":1786614111000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/jssc.70491"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7]]},"references-count":44,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2026,7]]}},"alternative-id":["10.1002\/jssc.70491"],"URL":"https:\/\/doi.org\/10.1002\/jssc.70491","archive":["Portico"],"relation":{},"ISSN":["1615-9306","1615-9314"],"issn-type":[{"value":"1615-9306","type":"print"},{"value":"1615-9314","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7]]},"assertion":[{"value":"2026-02-06","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-03","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-14","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e70491"}}