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After the characterization of the MOF\u2010coated fiber by Fourier\u2010transform infrared spectroscopy, scanning electron microscopy, and powder X\u2010ray diffraction, it was applied in both headspace (HS)\u2010 and direct immersion (DI)\u2010 SPME in combination with gas chromatography\u2010mass spectrometry. The studies were carried out in comparison with three commercial SPME fibers. Considering all the fibers studied, up to 52 and 26 compounds were tentatively identified via HS\u2010 and DI\u2010SPME, respectively. Besides, all fibers presented adequate reproducibility and similar lifetime, even in the DI mode and despite the sample complexity. In HS\u2010SPME, a total of 25 compounds were tentatively identified with the MOF\u2010coated fiber. From these analytes, 10 compounds (\u223c42%) were exclusively detected with the MOF\u2010coated fiber. In DI\u2010SPME, 10 compounds were tentatively identified with the MOF\u2010coated fiber, and four of these compounds (\u223c50%) were exclusively detected with this fiber. Overall, the results indicate that the MOF\u2010coated fiber offers a superior selectivity for heavier, less volatile, and less polar analytes, therefore acting as a complementary tool for commercial coatings when intending metabolomic studies for food analysis. The dual approach with MOF\u2010coated fiber and commercial SPME coatings provides more comprehensive information for food analysis.\n                  <\/jats:p>","DOI":"10.1002\/jssc.70543","type":"journal-article","created":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T03:30:38Z","timestamp":1790566238000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Dual Approach Combining Metal\u2010Organic Frameworks and Commercial Solid\u2010Phase Microextraction Coatings for Monitoring Volatiles in Passion Fruit"],"prefix":"10.1002","volume":"49","author":[{"given":"Montse","family":"Saura\u2010Cayuela","sequence":"first","affiliation":[{"name":"Laboratorio de Materiales para An\u00e1lisis Qu\u00edmico (MAT4LL) Departamento de Qu\u00edmica Facultad de Ciencias Universidad de La Laguna (ULL)  San Crist\u00f3bal de La Laguna Spain"},{"name":"Unidad de Investigaci\u00f3n de Bioanal\u00edtica y Medio Ambiente 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An\u00e1lisis Qu\u00edmico (MAT4LL) Departamento de Qu\u00edmica Facultad de Ciencias Universidad de La Laguna (ULL)  San Crist\u00f3bal de La Laguna Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Juan H.","family":"Ayala","sequence":"additional","affiliation":[{"name":"Laboratorio de Materiales para An\u00e1lisis Qu\u00edmico (MAT4LL) Departamento de Qu\u00edmica Facultad de Ciencias Universidad de La Laguna (ULL)  San Crist\u00f3bal de La Laguna Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ver\u00f3nica","family":"Pino","sequence":"additional","affiliation":[{"name":"Laboratorio de Materiales para An\u00e1lisis Qu\u00edmico (MAT4LL) Departamento de Qu\u00edmica Facultad de Ciencias Universidad de La Laguna (ULL)  San Crist\u00f3bal de La Laguna Spain"},{"name":"Unidad de Investigaci\u00f3n de Bioanal\u00edtica y Medio Ambiente Instituto Universitario de Enfermedades Tropicales y Salud P\u00fablica de Canarias (IUETSPC) Universidad de La Laguna (ULL)  San Crist\u00f3bal de La Laguna Spain"},{"name":"Centro de Investigaci\u00f3n Biom\u00e9dica en Red de Enfermedades Infecciosas (Ciberinfec) Instituto de Salud Carlos III Madrid Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mar\u00eda J.","family":"Trujillo\u2010Rodr\u00edguez","sequence":"additional","affiliation":[{"name":"Laboratorio de Materiales para An\u00e1lisis Qu\u00edmico (MAT4LL) Departamento de Qu\u00edmica Facultad de Ciencias Universidad de La Laguna (ULL)  San Crist\u00f3bal de La Laguna Spain"},{"name":"Unidad de Investigaci\u00f3n de Bioanal\u00edtica y Medio Ambiente Instituto Universitario de Enfermedades Tropicales y Salud P\u00fablica de Canarias (IUETSPC) Universidad de La Laguna (ULL)  San Crist\u00f3bal de La Laguna 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