{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,19]],"date-time":"2025-10-19T14:51:08Z","timestamp":1760885468912},"reference-count":40,"publisher":"Wiley","issue":"17","license":[{"start":{"date-parts":[[2010,7,27]],"date-time":"2010-07-27T00:00:00Z","timestamp":1280188800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2010,9]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Porous monolithic materials have been prepared via ring\u2010opening metathesis polymerization from norborn\u20102\u2010ene and a 7\u2010oxanorborn\u20102\u2010ene\u2010based cross\u2010linker in the presence of porogenic solvents (i.e., 2\u2010propanol and toluene) and norborn\u20102\u2010enephosphonate surface\u2010modified CaCO<jats:sub>3<\/jats:sub> nanoparticles, using the 3<jats:sup>rd<\/jats:sup>\u2010generation Grubbs\u2010initiator RuCl<jats:sub>2<\/jats:sub>(Py)<jats:sub>2<\/jats:sub>(IMesH<jats:sub>2<\/jats:sub>)(CHPh). The experimental setup and the conditions chosen allowed for the manufacturing of polymeric monoliths characterized by a homogeneous distribution of the inorganic nanoparticles throughout the polymeric monolith. Depending on the nanoparticle content, the macropore diameters could be varied in the 30\u2013120\u2009\u00b5m regime. Noteworthy, the addition of nanoparticles did not affect the phase separation\u2010triggered formation of the monolithic matrix nor the meso\u2010 and microporosity as evidenced by N<jats:sub>2<\/jats:sub>\u2010adsorption experiments.<\/jats:p><jats:p><jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" mimetype=\"image\/jpeg\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic\/mgra001.jpg\"><jats:alt-text>magnified image<\/jats:alt-text><\/jats:graphic><\/jats:boxed-text>\n<\/jats:p>","DOI":"10.1002\/marc.201000317","type":"journal-article","created":{"date-parts":[[2010,7,27]],"date-time":"2010-07-27T07:41:47Z","timestamp":1280216507000},"page":"1540-1545","source":"Crossref","is-referenced-by-count":15,"title":["Ring\u2010Opening Metathesis Polymerization\u2010Based Synthesis of CaCO<sub>3<\/sub> Nanoparticle\u2010Reinforced Polymeric Monoliths for Tissue Engineering"],"prefix":"10.1002","volume":"31","author":[{"given":"Franziska","family":"Weichelt","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bernhard","family":"Frerich","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Solvig","family":"Lenz","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Stefanie","family":"Tiede","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michael R.","family":"Buchmeiser","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2010,7,27]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.polymer.2007.02.045"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/macp.200600646"},{"key":"e_1_2_6_3_2","unstructured":"\u00a0"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(20000417)112:8<1491::AID-ANGE1491>3.0.CO;2-2"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(20000417)39:8<1433::AID-ANIE1433>3.0.CO;2-B"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma000322n"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma0609883"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.8134835"},{"key":"e_1_2_6_9_2","volume-title":"Medizintechnik mit biokompatiblen Werkstoffen und Verfahren","author":"Wintermantel E.","year":"2002"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0070-2153(04)61005-2"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/0142-9612(90)90038-R"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1006\/mthe.1999.0003"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar9800993"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1097-4644(199702)64:2<295::AID-JCB12>3.0.CO;2-I"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.284.5411.143"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/jor.1100160202"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1111\/j.1600-0501.2006.01295.x"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-3468(88)80529-3"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/jbm.820290807"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/pi.2108"},{"key":"e_1_2_6_21_2","unstructured":"\u00a0"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200801872"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200801872"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1723621"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/j150415a018"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01259a068"},{"key":"e_1_2_6_27_2","volume-title":"NATO Science Series II. Mathematics, Physics and Chemistry","author":"Buchmeiser M. R.","year":"2009"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/pola.23328"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/masy.201050115"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2007.11.016"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma900884f"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma061456p"},{"key":"e_1_2_6_33_2","unstructured":"\u00a0"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200250632"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200250632"},{"key":"e_1_2_6_36_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2008.05.232"},{"key":"e_1_2_6_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/jrs.806"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1007\/PL00012698"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1054\/ijom.2001.0130"},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcms.2006.07.860"}],"container-title":["Macromolecular Rapid Communications"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fmarc.201000317","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fmarc.201000317","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.201000317","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,12]],"date-time":"2023-09-12T06:11:48Z","timestamp":1694499108000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/marc.201000317"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2010,7,27]]},"references-count":40,"journal-issue":{"issue":"17","published-print":{"date-parts":[[2010,9]]}},"alternative-id":["10.1002\/marc.201000317"],"URL":"https:\/\/doi.org\/10.1002\/marc.201000317","archive":["Portico"],"relation":{},"ISSN":["1022-1336","1521-3927"],"issn-type":[{"value":"1022-1336","type":"print"},{"value":"1521-3927","type":"electronic"}],"subject":[],"published":{"date-parts":[[2010,7,27]]}}}