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Poly(diorganostannane)s are thermally stable with decomposition commencing above 200 \u00b0C. Poly(dialkylstannane)s can show liquid\u2010crystalline behavior around room temperature. They can be oriented by various procedures, whereby orientation of the polystannane main chain depends on the orientation procedure and the length of the alkyl side groups. Some of the oriented systems showed a pronounced dichroism. Polystannanes degrade under the action of light, in particular when in solution.<\/jats:p>","DOI":"10.1002\/marc.201100794","type":"journal-article","created":{"date-parts":[[2012,3,23]],"date-time":"2012-03-23T12:47:16Z","timestamp":1332506836000},"page":"448-460","source":"Crossref","is-referenced-by-count":35,"title":["Polystannanes: Synthesis, Properties, and Outlook"],"prefix":"10.1002","volume":"33","author":[{"given":"Markus","family":"Trummer","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fabien","family":"Choffat","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Paul","family":"Smith","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Walter","family":"Caseri","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2012,3,22]]},"reference":[{"key":"e_1_2_10_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00096a006"},{"key":"e_1_2_10_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00040a007"},{"key":"e_1_2_10_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00135a037"},{"key":"e_1_2_10_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma991556d"},{"key":"e_1_2_10_5_2","first-page":"556","volume":"2","author":"L\u00f6wig C.","year":"1852","journal-title":"Mitt. 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