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In pyridine, an improved control of the polymerization was also obtained for a non\u2010acid\u2010functional initiator, and the overall rate of polymerization increased. These effects are likely to be the result of the disruption of intramolecular hydrogen bonding and, in the case of pyridine, stabilization of the polar SG1 free radical.<\/jats:p>","DOI":"10.1002\/marc.201100866","type":"journal-article","created":{"date-parts":[[2012,2,21]],"date-time":"2012-02-21T16:44:26Z","timestamp":1329842666000},"page":"805-810","source":"Crossref","is-referenced-by-count":48,"title":["Use of Solvent Effects to Improve Control Over Nitroxide\u2010Mediated Polymerization of 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