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The nitroxide end group is exchanged for a thiocarbonylthio end group by a rapid transfer reaction with bis(thiobenzoyl) disulfide to generate in situ reversible addition\u2013fragmentation chain transfer (RAFT) macroinitiators. Moreover, not only have these macroinitiators been used in chain extension and block copolymerization experiments by the RAFT process but also a thiol\u2010terminated polymer is synthesized by aminolysis of the RAFT end group and subsequently reacted with dodecyl vinyl ether by thiol\u2010ene chemistry.<\/jats:p>","DOI":"10.1002\/marc.201200207","type":"journal-article","created":{"date-parts":[[2012,5,25]],"date-time":"2012-05-25T08:30:53Z","timestamp":1337934653000},"page":"1310-1315","source":"Crossref","is-referenced-by-count":24,"title":["From NMP to RAFT and Thiol\u2010Ene Chemistry by In Situ Functionalization of Nitroxide Chain Ends"],"prefix":"10.1002","volume":"33","author":[{"given":"Lionel","family":"Petton","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andr\u00e9s E.","family":"Ciolino","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Milan M.","family":"Stamenovi\u0107","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pieter","family":"Espeel","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Filip E.","family":"Du Prez","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2012,5,25]]},"reference":[{"key":"e_1_2_4_1_2","unstructured":"D. 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