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In a two\u2010phase system, the polymer in the aqueous phase could move to the chloroform phase on raising the temperature above its LCST. This temperature\u2010driven process results in the formation of polymeric toroids in the chloroform phase, and the strategy affords a new pathway to toroidal self\u2010assembly of polymers. Moreover, the photoluminescent behavior of the RhB end\u2010capped PNIPAAm species formed by the process is also studied and discussed.<jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" mimetype=\"image\/jpeg\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic\/mgra001.jpg\"><jats:alt-text>magnified image<\/jats:alt-text><\/jats:graphic><\/jats:boxed-text><\/jats:p>","DOI":"10.1002\/marc.201300038","type":"journal-article","created":{"date-parts":[[2013,3,14]],"date-time":"2013-03-14T00:19:53Z","timestamp":1363220393000},"page":"689-694","source":"Crossref","is-referenced-by-count":12,"title":["Photoluminescent Toroids Formed by Temperature\u2010Driven Self\u2010Assembly of Rhodamine B End\u2010Capped 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