{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T23:42:27Z","timestamp":1789688547709,"version":"4.0.1"},"reference-count":31,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2013,10,11]],"date-time":"2013-10-11T00:00:00Z","timestamp":1381449600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2014,1]]},"abstract":"<jats:p>This contribution describes the synthesis of block copolymers containing electrochemically active blocks, their micellization, and finally their use as micellar cathodes in a lithium battery. The self\u2010assembly of the synthesized poly(styrene)\u2010<jats:italic>block<\/jats:italic>\u2010poly(2,2,6,6\u2010tetramethylpiperidinyloxy\u20104\u2010yl methacrylate) (PS\u2010<jats:italic>b<\/jats:italic>\u2010PTMA) diblock copolymers is realized in a typical battery electrolyte made of 1 <jats:sc>m<\/jats:sc> lithium trifluoromethanesulfonate dissolved in a mixture of ethylene carbonate\/diethyl carbonate\/dimethyl carbonate(1:1:1, in volume). Dynamic light scattering and atomic force micro\u00adscopy indicate the formation of well\u2010defined spherical micelles with a PS core and a PTMA corona. The electrochemical properties of those micelles are further investigated. Cyclic voltammograms show a reversible redox reaction at 3.6 V (vs Li<jats:sup>+<\/jats:sup>\/Li). The charge\/discharge profiles indicate a flat and reversible plateau around 3.6 V (vs Li<jats:sup>+<\/jats:sup>\/Li). Finally, the cycling performances of the micellar cathodes are demonstrated. Such self\u2010assembled block copolymers open new opportunities for nanostructured organic radical batteries.\n<jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" mimetype=\"image\/jpg\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic\/marc201300532-abs-0001-m.jpg\"><jats:alt-text>image<\/jats:alt-text><\/jats:graphic><\/jats:boxed-text><\/jats:p>","DOI":"10.1002\/marc.201300532","type":"journal-article","created":{"date-parts":[[2013,10,14]],"date-time":"2013-10-14T11:55:01Z","timestamp":1381751701000},"page":"228-233","source":"Crossref","is-referenced-by-count":52,"title":["Micellar Cathodes from Self\u2010Assembled Nitroxide\u2010Containing Block Copolymers in Battery Electrolytes"],"prefix":"10.1002","volume":"35","author":[{"given":"Guillaume","family":"Hauffman","sequence":"first","affiliation":[{"name":"Institute of Condensed Matter and Nanosciences (IMCN), Bio\u2010 and Soft Matter (BSMA) Universit\u00e9 catholique de Louvain  Place L. Pasteur, 1 1348 Louvain la Neuve Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Quentin","family":"Maguin","sequence":"additional","affiliation":[{"name":"Institute of Condensed Matter and Nanosciences (IMCN), Bio\u2010 and Soft Matter (BSMA) Universit\u00e9 catholique de Louvain  Place L. Pasteur, 1 1348 Louvain la Neuve Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jean\u2010Pierre","family":"Bourgeois","sequence":"additional","affiliation":[{"name":"Institute of Condensed Matter and Nanosciences (IMCN), Bio\u2010 and Soft Matter (BSMA) Universit\u00e9 catholique de Louvain  Place L. Pasteur, 1 1348 Louvain la Neuve Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexandru","family":"Vlad","sequence":"additional","affiliation":[{"name":"Information and Communication Technologies Electronics and Applied Mathematics (ICTEAM) Universit\u00e9 catholique de Louvain  Place de Levant, 3 1348 Louvain la Neuve Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jean\u2010Fran\u00e7ois","family":"Gohy","sequence":"additional","affiliation":[{"name":"Institute of Condensed Matter and Nanosciences (IMCN), Bio\u2010 and Soft Matter (BSMA) Universit\u00e9 catholique de Louvain  Place L. 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