{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T10:48:41Z","timestamp":1789728521844,"version":"4.0.1"},"reference-count":33,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2014,9,23]],"date-time":"2014-09-23T00:00:00Z","timestamp":1411430400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"IUPAC, DFG"},{"name":"Graduate School MAINZ"},{"DOI":"10.13039\/100005156","name":"Alexander von Humboldt Foundation","doi-asserted-by":"crossref","id":[{"id":"10.13039\/100005156","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2015,1]]},"abstract":"<jats:p>The preparation of poly(isobutylene) (PIB) nanoparticles via cationic emulsion polymerization is presented. As a requirement, an oil\u2010in\u2010perfluoroalkane nonaqueous emulsion is developed, which is inert under the carbocationic polymerization conditions. To stabilize the dichloromethane\/hexane droplets in the fluorinated, continuous phase, an amphiphilic block copolymer emulsifier is prepared containing PIB and 1<jats:italic>H<\/jats:italic>,1<jats:italic>H<\/jats:italic>\u2010perfluoroalkylated poly(pentafluorostyrene) blocks. This system allows for the polymerization of isobutylene with number\u2010average molecular weights (<jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/marc201400401-math-0001.png\" xlink:title=\"urn:x-wiley:dummy:marc201400401:equation:marc201400401-math-0001\"\/>) up to 27 000 g mol<jats:sup>\u22121<\/jats:sup>. The particle morphologies are characterized via dynamic light scattering and electron microscopy. For <jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/marc201400401-math-0002.png\" xlink:title=\"urn:x-wiley:dummy:marc201400401:equation:marc201400401-math-0002\"\/> &gt; 20 000 g mol<jats:sup>\u22121<\/jats:sup>, the particles exhibit shape\u2010persistence at room temperature and are \u2248100 nm in diameter.\n<jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" mimetype=\"image\/png\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic\/marc201400401-abs-0001-m.png\"><jats:alt-text>image<\/jats:alt-text><\/jats:graphic><\/jats:boxed-text><\/jats:p>","DOI":"10.1002\/marc.201400401","type":"journal-article","created":{"date-parts":[[2014,9,23]],"date-time":"2014-09-23T17:54:08Z","timestamp":1411494848000},"page":"204-210","source":"Crossref","is-referenced-by-count":7,"title":["Poly(isobutylene) Nanoparticles via Cationic Polymerization in Nonaqueous Emulsions"],"prefix":"10.1002","volume":"36","author":[{"given":"Thomas","family":"Schuster","sequence":"first","affiliation":[{"name":"Max Planck Institute for Polymer Research  Ackermannweg 10 55128 Mainz Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Florian E.","family":"Golling","sequence":"additional","affiliation":[{"name":"Max Planck Institute for Polymer Research  Ackermannweg 10 55128 Mainz Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Joseph W.","family":"Krumpfer","sequence":"additional","affiliation":[{"name":"Max Planck Institute for Polymer Research  Ackermannweg 10 55128 Mainz Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manfred","family":"Wagner","sequence":"additional","affiliation":[{"name":"Max Planck Institute for Polymer Research  Ackermannweg 10 55128 Mainz Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Robert","family":"Graf","sequence":"additional","affiliation":[{"name":"Max Planck Institute for Polymer Research  Ackermannweg 10 55128 Mainz Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Abdulhamid A.","family":"Alsaygh","sequence":"additional","affiliation":[{"name":"King Abdulaziz City for Science and Technology (KACST)  PO BOX 6086 Riyadh 11442 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Markus","family":"Klapper","sequence":"additional","affiliation":[{"name":"Max Planck Institute for Polymer Research  Ackermannweg 10 55128 Mainz Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Klaus","family":"M\u00fcllen","sequence":"additional","affiliation":[{"name":"Max Planck Institute for Polymer Research  Ackermannweg 10 55128 Mainz Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2014,9,23]]},"reference":[{"key":"e_1_2_6_1_1","volume-title":"Handbook of Pressure Sensitive Adhesives and Products","author":"Willenbacher N. 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