{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T05:11:10Z","timestamp":1791177070897,"version":"4.1.0"},"reference-count":43,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2014,12,4]],"date-time":"2014-12-04T00:00:00Z","timestamp":1417651200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2015,4]]},"abstract":"<jats:p>Poly(<jats:italic>N,N<\/jats:italic>\u2010dimethylaminoethyl methacrylate) (PDMAEMA) has been reported to show both upper critical solution temperature (UCST) and lower critical solution temperature (LCST) behavior in presence of trivalent metal hexacyano anions, which is attractive for the development of smart materials. In this communication, the influence of the double thermoresponsive behavior of PDMAEMA driven by electrostatic interactions is investigated by comparing systems with [Co(CN)<jats:sub>6<\/jats:sub>]<jats:sup>3\u2212<\/jats:sup>, [Fe(CN)<jats:sub>6<\/jats:sub>]<jats:sup>3\u2212<\/jats:sup>, and [Cr(CN)<jats:sub>6<\/jats:sub>]<jats:sup>3\u2212<\/jats:sup> as trivalent anions. Furthermore, tuning of double thermoresponsive behavior of PDMAEMA by incorporating hydrophilic or hydrophobic comonomers is also discussed in the presence of [Fe(CN)<jats:sub>6<\/jats:sub>]<jats:sup>3\u2212<\/jats:sup> as trivalent ion.\n<jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" mimetype=\"image\/png\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic\/marc201400550-abs-0001-m.png\"><jats:alt-text>image<\/jats:alt-text><\/jats:graphic><\/jats:boxed-text><\/jats:p>","DOI":"10.1002\/marc.201400550","type":"journal-article","created":{"date-parts":[[2014,12,6]],"date-time":"2014-12-06T11:38:55Z","timestamp":1417865935000},"page":"633-639","source":"Crossref","is-referenced-by-count":60,"title":["Tuning the LCST and UCST Thermoresponsive Behavior of Poly(<b><i>N,N<\/i><\/b>\u2010dimethylaminoethyl methacrylate) by Electrostatic Interactions with Trivalent Metal Hexacyano Anions and Copolymerization"],"prefix":"10.1002","volume":"36","author":[{"given":"Qilu","family":"Zhang","sequence":"first","affiliation":[{"name":"Supramolecular Chemistry Group Department of Organic and Macromolecular Chemistry Ghent University  Krijgslaan 281 S4 B\u20109000 Gent Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Filippo","family":"Tosi","sequence":"additional","affiliation":[{"name":"Supramolecular Chemistry Group Department of Organic and Macromolecular Chemistry Ghent University  Krijgslaan 281 S4 B\u20109000 Gent Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sibel","family":"\u00dc\u01e7d\u00fcler","sequence":"additional","affiliation":[{"name":"Supramolecular Chemistry Group Department of Organic and Macromolecular Chemistry Ghent University  Krijgslaan 281 S4 B\u20109000 Gent Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Samarendra","family":"Maji","sequence":"additional","affiliation":[{"name":"Supramolecular Chemistry Group Department of Organic and Macromolecular Chemistry Ghent University  Krijgslaan 281 S4 B\u20109000 Gent Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Richard","family":"Hoogenboom","sequence":"additional","affiliation":[{"name":"Supramolecular Chemistry Group Department of Organic and Macromolecular Chemistry Ghent University  Krijgslaan 281 S4 B\u20109000 Gent Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2014,12,4]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs35499g"},{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1039\/B406727D"},{"key":"e_1_2_6_1_3","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejpb.2007.02.025"},{"key":"e_1_2_6_1_4","doi-asserted-by":"publisher","DOI":"10.1039\/C3PY00971H"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1080\/10601326808051910"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/0079-6700(92)90023-R"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2014.02.005"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/pola.22706"},{"key":"e_1_2_6_3_3","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201100597"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200901607"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2011.10.002"},{"key":"e_1_2_6_4_3","doi-asserted-by":"publisher","DOI":"10.3390\/polym3010467"},{"key":"e_1_2_6_4_4","doi-asserted-by":"publisher","DOI":"10.1039\/b813140f"},{"key":"e_1_2_6_4_5","doi-asserted-by":"publisher","DOI":"10.1002\/marc.201200354"},{"key":"e_1_2_6_4_6","doi-asserted-by":"publisher","DOI":"10.1002\/marc.200900683"},{"key":"e_1_2_6_4_7","doi-asserted-by":"publisher","DOI":"10.1039\/C0PY00291G"},{"key":"e_1_2_6_4_8","doi-asserted-by":"publisher","DOI":"10.1021\/ma802592f"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/marc.201200433"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma011533a"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1023\/A:1020623213658"},{"key":"e_1_2_6_6_3","doi-asserted-by":"publisher","DOI":"10.1039\/B919759A"},{"key":"e_1_2_6_6_4","doi-asserted-by":"publisher","DOI":"10.1021\/ma201528r"},{"key":"e_1_2_6_6_5","doi-asserted-by":"publisher","DOI":"10.1021\/bm900208u"},{"key":"e_1_2_6_6_6","doi-asserted-by":"publisher","DOI":"10.1002\/marc.201000713"},{"key":"e_1_2_6_6_7","doi-asserted-by":"publisher","DOI":"10.1002\/macp.201300552"},{"key":"e_1_2_6_7_1","first-page":"126","volume":"5","author":"Pae B. 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