{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2024,6,20]],"date-time":"2024-06-20T09:54:45Z","timestamp":1718877285833},"reference-count":30,"publisher":"Wiley","issue":"13","license":[{"start":{"date-parts":[[2015,5,8]],"date-time":"2015-05-08T00:00:00Z","timestamp":1431043200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"NSF","award":["DMR-1410568","CMMI-1246804"],"award-info":[{"award-number":["DMR-1410568","CMMI-1246804"]}]},{"name":"ONR YIP","award":["N000141210657"],"award-info":[{"award-number":["N000141210657"]}]},{"name":"3M Nontenured Faculty Award"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2015,7]]},"abstract":"<jats:p>The fabrication of block copolymer (BCP) thin films is reported with vertically aligned cylindrical domains using continuous electrospray deposition onto bare wafer surfaces. The out\u2010of\u2010plane orientation of hexagonally packed styrene cylinders is achieved in the \u201cfast\u2010wet\u201d deposition regime in which rapid evaporation of the solvent in deposited droplets of polymer solution drives the vertical alignment of the self\u2010assembled structure. Thermally activated crosslinking of the polybutadiene matrix provides kinetic control of the morphology, freezing the vertical alignment and preventing relaxation of the system to its preferred parallel orientation on the nontreated substrate. Physically continuous vertically oriented domains can be achieved over several micrometers of film thickness. The ability of electrospray deposition to fabricate well\u2010ordered and aligned BCP films on nontreated substrates, the low amount of material used relative to spin\u2010coating, and the continuous nature of the deposition may open up new opportunities for BCP thin films.\n<jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" mimetype=\"image\/png\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic\/marc201500099-abs-0001-m.png\"><jats:alt-text>image<\/jats:alt-text><\/jats:graphic><\/jats:boxed-text><\/jats:p>","DOI":"10.1002\/marc.201500099","type":"journal-article","created":{"date-parts":[[2015,5,8]],"date-time":"2015-05-08T19:39:54Z","timestamp":1431113994000},"page":"1290-1296","source":"Crossref","is-referenced-by-count":11,"title":["Physical Continuity and Vertical Alignment of Block Copolymer Domains by Kinetically Controlled Electrospray Deposition"],"prefix":"10.1002","volume":"36","author":[{"given":"Hanqiong","family":"Hu","sequence":"first","affiliation":[{"name":"Department of Chemical Engineering Yale University  New Haven CT 06511 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Youngwoo","family":"Choo","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering Yale University  New Haven CT 06511 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xunda","family":"Feng","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering Yale University  New Haven CT 06511 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chinedum O.","family":"Osuji","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering Yale University  New Haven CT 06511 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2015,5,8]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3sm52607k"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja107309p"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200501500"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl2013554"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.290.5499.2126"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl801105s"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.200801831"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1162950"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1157626"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1088\/0957-4484\/16\/7\/003"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.275.5305.1458"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200602708"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma8018393"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200304906"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma1012946"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja3126382"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/marc.201300845"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma9002903"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn403847z"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1226046"},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201401678"},{"key":"e_1_2_6_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn400279a"},{"key":"e_1_2_6_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma500376n"},{"key":"e_1_2_6_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma062393d"},{"key":"e_1_2_6_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-8502(96)00433-8"},{"key":"e_1_2_6_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma971349i"},{"key":"e_1_2_6_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/mz400572r"},{"key":"e_1_2_6_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/pen.10295"},{"key":"e_1_2_6_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/0014-3057(78)90132-5"},{"key":"e_1_2_6_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.polymertesting.2010.02.008"}],"container-title":["Macromolecular Rapid Communications"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fmarc.201500099","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fmarc.201500099","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.201500099","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,4]],"date-time":"2023-10-04T04:52:50Z","timestamp":1696395170000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/marc.201500099"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,5,8]]},"references-count":30,"journal-issue":{"issue":"13","published-print":{"date-parts":[[2015,7]]}},"alternative-id":["10.1002\/marc.201500099"],"URL":"https:\/\/doi.org\/10.1002\/marc.201500099","archive":["Portico"],"relation":{},"ISSN":["1022-1336","1521-3927"],"issn-type":[{"value":"1022-1336","type":"print"},{"value":"1521-3927","type":"electronic"}],"subject":[],"published":{"date-parts":[[2015,5,8]]}}}