{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,29]],"date-time":"2026-04-29T20:54:30Z","timestamp":1777496070901,"version":"3.51.4"},"reference-count":40,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2016,7,4]],"date-time":"2016-07-04T00:00:00Z","timestamp":1467590400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2016,9]]},"abstract":"<jats:p>In this work, the synthesis of various halogenated thiophenol derivatives is presented. These thiophenols are used as monomers in light\u2010initiated S<jats:sub>RN<\/jats:sub>1\u2010type radical polymerization reactions. The method provides easy access to industrially relevant poly(paraphenylene sulfide) and poly(metaphenylene sulfide). The influence of the halide leaving group and of other substituents in the thiophenol monomer on the polymerization process is investigated.\n<jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" mimetype=\"image\/png\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic\/marc201600254-abs-0001-m.png\"><jats:alt-text>image<\/jats:alt-text><\/jats:graphic><\/jats:boxed-text>\n<\/jats:p>","DOI":"10.1002\/marc.201600254","type":"journal-article","created":{"date-parts":[[2016,7,4]],"date-time":"2016-07-04T16:36:49Z","timestamp":1467650209000},"page":"1494-1498","source":"Crossref","is-referenced-by-count":5,"title":["Poly(paraphenylene sulfide) and Poly(metaphenylene sulfide) via Light\u2010Initiated S<sub>RN<\/sub>1\u2010Type Polymerization of Halogenated Thiophenols"],"prefix":"10.1002","volume":"37","author":[{"given":"Niklas B.","family":"Heine","sequence":"first","affiliation":[{"name":"Organic Chemistry Institute Westf\u00e4lische Wilhelms\u2010Universit\u00e4t  Corrensstra\u00dfe 40 48149 M\u00fcnster Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Armido","family":"Studer","sequence":"additional","affiliation":[{"name":"Organic Chemistry Institute Westf\u00e4lische Wilhelms\u2010Universit\u00e4t  Corrensstra\u00dfe 40 48149 M\u00fcnster Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2016,7,4]]},"reference":[{"key":"e_1_2_5_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201409468"},{"key":"e_1_2_5_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1624"},{"key":"e_1_2_5_3_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-94-011-7073-4"},{"key":"e_1_2_5_4_1","volume-title":"Ullmann's Encyclopedia of Industrial Chemistry","author":"Parker D.","year":"2003"},{"key":"e_1_2_5_5_1","doi-asserted-by":"publisher","DOI":"10.1080\/07366578908055165"},{"key":"e_1_2_5_6_1","doi-asserted-by":"publisher","DOI":"10.1515\/revce-2012-0021"},{"key":"e_1_2_5_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo01159a020"},{"key":"e_1_2_5_8_1","unstructured":"J. J. T.Edmonds J. H. W.Hill Jr. (US Patent) US 3354129 1963."},{"key":"e_1_2_5_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/macp.1985.020121985110"},{"key":"e_1_2_5_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/masy.19920540122"},{"key":"e_1_2_5_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2009.02.068"},{"key":"e_1_2_5_12_1","doi-asserted-by":"publisher","DOI":"10.1080\/10601329008544827"},{"key":"e_1_2_5_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/macp.1983.021840412"},{"key":"e_1_2_5_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma961760q"},{"key":"e_1_2_5_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)85416-7"},{"key":"e_1_2_5_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201206096"},{"key":"e_1_2_5_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00975a061"},{"key":"e_1_2_5_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00975a063"},{"key":"e_1_2_5_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr400689s"},{"key":"e_1_2_5_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo00938a044"},{"key":"e_1_2_5_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo00935a037"},{"key":"e_1_2_5_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00728a037"},{"key":"e_1_2_5_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00728a038"},{"key":"e_1_2_5_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/pol.1982.180201003"},{"key":"e_1_2_5_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3935(20011001)202:14<2832::AID-MACP2832>3.0.CO;2-V"},{"key":"e_1_2_5_26_1","doi-asserted-by":"publisher","DOI":"10.1080\/00304947809355044"},{"key":"e_1_2_5_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr960134o"},{"key":"e_1_2_5_27_2","first-page":"333","volume-title":"Encyclopedia of Radicals in Chemistry, Biology and Materials","author":"Bardag\u00ed J. I.","year":"2012"},{"key":"e_1_2_5_28_1","doi-asserted-by":"publisher","DOI":"10.1080\/00304947809355044"},{"key":"e_1_2_5_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2031"},{"key":"e_1_2_5_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201505090"},{"key":"e_1_2_5_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo01350a023"},{"key":"e_1_2_5_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2005.12.063"},{"key":"e_1_2_5_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(97)00268-8"},{"key":"e_1_2_5_33_1","doi-asserted-by":"publisher","DOI":"10.1055\/s-2008-1032179"},{"key":"e_1_2_5_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo01068a097"},{"key":"e_1_2_5_35_1","doi-asserted-by":"publisher","DOI":"10.1248\/cpb.33.5184"},{"key":"e_1_2_5_36_1","doi-asserted-by":"publisher","DOI":"10.1055\/s-2003-36251"},{"key":"e_1_2_5_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19681010847"},{"key":"e_1_2_5_38_1","doi-asserted-by":"publisher","DOI":"10.1055\/s-0030-1258385"}],"container-title":["Macromolecular Rapid Communications"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fmarc.201600254","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.201600254","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,6]],"date-time":"2023-10-06T16:17:26Z","timestamp":1696609046000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/marc.201600254"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,7,4]]},"references-count":40,"journal-issue":{"issue":"18","published-print":{"date-parts":[[2016,9]]}},"alternative-id":["10.1002\/marc.201600254"],"URL":"https:\/\/doi.org\/10.1002\/marc.201600254","archive":["Portico"],"relation":{},"ISSN":["1022-1336","1521-3927"],"issn-type":[{"value":"1022-1336","type":"print"},{"value":"1521-3927","type":"electronic"}],"subject":[],"published":{"date-parts":[[2016,7,4]]}}}