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Rapid Commun."],"published-print":{"date-parts":[[2018,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Helical structures at different scales endow functional materials with special optical, electrical, and magnetic properties. However, methods for constructing and regulating single\u2010handed helicity, particularly complex 3D hierarchical structures, remain limited. In this study, co\u2010self\u2010assembly process combined with emulsion droplets is used to produce the various well\u2010defined 3D hollow superstructures of conducting polyaniline (PANI) with single\u2010handed helicity. The chirality of PANI is induced using enantiomeric <jats:italic><jats:sc>r<\/jats:sc><\/jats:italic>\u2010 or <jats:italic>s<\/jats:italic>\u2010camphorsulfonic acid as a dopant; the chirality of the dopant is then transferred to the supramolecular chirality of PANI assemblies and consequently to the helicity of 3D superstructures by incorporating emulsion droplets to serve collectively as soft templates. The twisting and anisotropism of these superstructures vary with the enhancement of the supramolecular chirality and result in the transformation of their morphologies from seashell\u2010like to spindle\u2010like and their cavity becoming more slender than their original shape. Due to the supramolecular chirality and hierarchical characteristics of these superstructures, enhanced microwave absorption performance is observed under a filler content of as low as 20 wt%, suggesting their promising application as microwave absorbers.<\/jats:p>","DOI":"10.1002\/marc.201700591","type":"journal-article","created":{"date-parts":[[2017,11,20]],"date-time":"2017-11-20T07:02:47Z","timestamp":1511161367000},"source":"Crossref","is-referenced-by-count":39,"title":["Self\u2010Assembled 3D Helical Hollow Superstructures with Enhanced Microwave Absorption Properties"],"prefix":"10.1002","volume":"39","author":[{"given":"Yang","family":"Yang","sequence":"first","affiliation":[{"name":"CAS Key Laboratory of Nanosystem and Hierarchical Fabrication CAS Center for Excellence in Nanoscience National Center for Nanoscience and Technology  Beijing 100190 China"},{"name":"University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jianqi","family":"Zhang","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Nanosystem and Hierarchical Fabrication CAS Center for Excellence in Nanoscience National Center for Nanoscience and Technology  Beijing 100190 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wenjun","family":"Zou","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Nanosystem and Hierarchical Fabrication CAS Center for Excellence in Nanoscience National Center for Nanoscience and Technology  Beijing 100190 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sai","family":"Wu","sequence":"additional","affiliation":[{"name":"Beijing Institute of Aeronautical Materials Aero Engine Corporation of China  Beijing 100095 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Fan","family":"Wu","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Disaster Prevention and Mitigation of Explosion and Impact PLA University of Science and Technology  Nanjing 210007 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Aming","family":"Xie","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Disaster Prevention and Mitigation of Explosion and Impact PLA University of Science and Technology  Nanjing 210007 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6188-3634","authenticated-orcid":false,"given":"Zhixiang","family":"Wei","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Nanosystem and Hierarchical Fabrication CAS Center for Excellence in Nanoscience National Center for Nanoscience and Technology  Beijing 100190 China"},{"name":"University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2017,11,20]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/171737a0"},{"key":"e_1_2_7_1_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1150577"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0092-8674(00)80205-6"},{"key":"e_1_2_7_3_1","doi-asserted-by":"crossref","first-page":"1133","DOI":"10.1038\/srep01133","volume":"3","author":"Kosuge K.","year":"2013","journal-title":"Sci. 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