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Rapid Commun."],"published-print":{"date-parts":[[2018,9]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Aspartate incorporated into the protein structure of mussel byssal threads is believed to play an important role, besides the reversible histidine\u2013zinc interactions, in the self\u2010healing behavior of mussel byssal threads. Therefore, copolymers containing both aspartate and histidine moieties are synthesized in order to investigate the influence of aspartate on the complexation of zinc(II) as well as on the self\u2010healing behavior and the mechanical properties of the resulting supramolecular networks. For this purpose, isothermal titration calorimetry measurements of a model aspartate compound as well as of these copolymers are performed and the thermodynamic parameters are utilized for the design of self\u2010healing copolymers. For this purpose, <jats:italic>n<\/jats:italic>\u2010lauryl methacrylate\u2010based copolymers containing histidine and aspartate are synthesized and crosslinked with zinc(II) acetate. The self\u2010healing behavior of the supramolecular networks is investigated using scratch healing tests and the mechanical properties by nanoindentation.<\/jats:p>","DOI":"10.1002\/marc.201700742","type":"journal-article","created":{"date-parts":[[2018,4,20]],"date-time":"2018-04-20T07:27:44Z","timestamp":1524209264000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Influence of Aspartate Moieties on the Self\u2010Healing Behavior of Histidine\u2010Rich Supramolecular Polymers"],"prefix":"10.1002","volume":"39","author":[{"given":"Marcel","family":"Enke","sequence":"first","affiliation":[{"name":"Laboratory of Organic and Macromolecular Chemistry (IOMC) Friedrich Schiller University Jena  Humboldtstr. 10 07743 Jena Germany"},{"name":"Jena Center for Soft Matter (JCSM) Friedrich Schiller University Jena  Philosophenweg 7 07743 Jena 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