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Rapid Commun."],"published-print":{"date-parts":[[2018,6]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Emissive organometallic polymers are an important class of functional materials characterized by the combined photoluminescent features of organometallic molecules and the properties of traditional polymers. In this work, the emissive organometallic complex, [CuBr(PPh<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(4\u2010methylpyridine)], is successfully, mechanically ground into a random copolymer built on 4\u2010(diphenylphosphino)styrene (DPVP) and <jats:italic>n<\/jats:italic>\u2010butyl acrylate (BA) monomers. The resultant hybrid materials successfully inherit the emissive centers, and are significantly reinforced by the copper complexes as chemical crosslinkers in the polymeric continuum. These organometallic polymers are also proved to have excellent vapoluminescent properties, exhibiting unique responses to many organic solvent vapors, reflecting their rapid loss and recovery of photoluminescence. Mechanically robust and flexible films prepared with these organometallic Cu(I)\u2010polymers are tested as recoverable sensors for hazardous volatile chemical compounds (VOCs) such as toluene, acetone, chloroform, and dichloromethane, and the low limits of detection (LOD) can reach as low as 1 \u00d7 10<jats:sup>\u22123<\/jats:sup>\u20138 \u00d7 10<jats:sup>\u22123<\/jats:sup> mg L<jats:sup>\u22121<\/jats:sup> (0.2\u20133.3 ppmV, parts per million\u2010volume) for various VOCs. This work sheds lights on the design and fabrication of organometallic polymers for advanced applications.<\/jats:p>","DOI":"10.1002\/marc.201800165","type":"journal-article","created":{"date-parts":[[2018,5,10]],"date-time":"2018-05-10T08:26:24Z","timestamp":1525940784000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Robust and Reversible Vapoluminescent Organometallic Copper Polymers"],"prefix":"10.1002","volume":"39","author":[{"given":"Hao","family":"Peng","sequence":"first","affiliation":[{"name":"Department of Chemistry and Chemical Engineering Southeast University  Nanjing Jiangsu 211189 P. R. China"},{"name":"Jiangsu Hi\u2010Tech Key Laboratory for Biomedical Research  Nanjing Jiangsu 211189 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yumeng","family":"Xin","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Engineering Southeast University  Nanjing Jiangsu 211189 P. R. China"},{"name":"Jiangsu Hi\u2010Tech Key Laboratory for Biomedical Research  Nanjing Jiangsu 211189 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wei","family":"Shen","sequence":"additional","affiliation":[{"name":"Department of Biomedical Engineering College of Engineering and Applied Sciences Nanjing National Laboratory of Microstructures Nanjing University  Nanjing Jiangsu 210093 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zhengtao","family":"Deng","sequence":"additional","affiliation":[{"name":"Department of Biomedical Engineering College of Engineering and Applied Sciences Nanjing National Laboratory of Microstructures Nanjing University  Nanjing Jiangsu 210093 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9501-5381","authenticated-orcid":false,"given":"Jiuyang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Engineering Southeast University  Nanjing Jiangsu 211189 P. R. China"},{"name":"Jiangsu Hi\u2010Tech Key Laboratory for Biomedical Research  Nanjing Jiangsu 211189 P. R. 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