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Rapid Commun."],"published-print":{"date-parts":[[2018,10]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Understanding the self\u2010assembly behavior of polymers of various topologies is key to a reliable design of functional polymer materials. Self\u2010assembly under confinement conditions emerges as a versatile avenue to design polymer particles with complex internal morphologies while simultaneously facilitating scale\u2010up. However, only linear block copolymers have been studied to date, despite the increasing control over macromolecule composition and architecture available. This study extends the investigation of polymer self\u2010assembly in confinement from regular diblock copolymers to diblock molecular polymer brushes (MPBs). Block\u2010type MPBs with polystyrene (PS) and polylactide (PLA) compartments of different sizes are incorporated into surfactant\u2010stabilized oil\u2010in\u2010water (chloroform\/water) emulsions. The increasing confinement in the nanoemulsion droplets during solvent evaporation directs the MPBs to form solid nano\/microparticles. Microscopy studies reveal an intricate internal particle structure, including interpenetrating networks and axially stacked lamellae of PS and PLA, depending on the PS\/PLA ratio of the brushes.<\/jats:p>","DOI":"10.1002\/marc.201800177","type":"journal-article","created":{"date-parts":[[2018,5,2]],"date-time":"2018-05-02T15:19:04Z","timestamp":1525274344000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":53,"title":["Self\u2010Assembly of Diblock Molecular Polymer Brushes in the Spherical Confinement of Nanoemulsion Droplets"],"prefix":"10.1002","volume":"39","author":[{"given":"Andrea","family":"Steinhaus","sequence":"first","affiliation":[{"name":"Physical Chemistry and Center for Nanointegration Duisburg\u2010Essen (CENIDE) University Duisburg\u2010Essen  47057 Duisburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Th\u00e9ophile","family":"Pelras","sequence":"additional","affiliation":[{"name":"Key Centre for Polymers and Colloids School of Chemistry, and The University of Sydney Nano Institute (Sydney Nano) The University of Sydney  NSW 2006 Sydney Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ramzi","family":"Chakroun","sequence":"additional","affiliation":[{"name":"Physical Chemistry and Center for Nanointegration Duisburg\u2010Essen (CENIDE) University Duisburg\u2010Essen  47057 Duisburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2576-394X","authenticated-orcid":false,"given":"Andr\u00e9 H.","family":"Gr\u00f6schel","sequence":"additional","affiliation":[{"name":"Physical Chemistry and Center for Nanointegration Duisburg\u2010Essen (CENIDE) University Duisburg\u2010Essen  47057 Duisburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0298-554X","authenticated-orcid":false,"given":"Markus","family":"M\u00fcllner","sequence":"additional","affiliation":[{"name":"Key Centre for Polymers and Colloids School of Chemistry, and The University of Sydney Nano Institute (Sydney Nano) The University of Sydney  NSW 2006 Sydney Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,5,2]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201200310"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5NR02448J"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.6b02355"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2016.24"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat1230"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/polb.22374"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.6b04700"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200801377"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3sm52821a"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.6b08342"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja4019447"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3py00750b"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja502075f"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.5b00350"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.5b04222"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7PY01817G"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2010.02.039"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.5b00335"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/macp.201600086"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.polymer.2016.03.076"},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/pola.20900"},{"key":"e_1_2_6_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2008.05.001"},{"key":"e_1_2_6_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00329B"},{"key":"e_1_2_6_24_1","author":"Pelras T.","year":"2018","journal-title":"Angew. 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