{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T19:02:46Z","timestamp":1759777366369,"version":"3.41.2"},"reference-count":25,"publisher":"Wiley","issue":"16","license":[{"start":{"date-parts":[[2019,6,25]],"date-time":"2019-06-25T00:00:00Z","timestamp":1561420800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100007601","name":"Horizon 2020","doi-asserted-by":"publisher","award":["642083"],"award-info":[{"award-number":["642083"]}],"id":[{"id":"10.13039\/501100007601","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2019,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The synthesis of a new class of Cu\u2010mediated polymerization initiators with thioester functionality is demonstrated and their polymerization kinetics via single\u2010electron transfer living radical polymerization is reported. From periodic sampling, it is found that thioester\u2010 or ester\u2010based initiators can be employed interchangeably, resulting in very similar polymerization rates. Furthermore, a multifunctional thioester initiator is employed for the preparation of a well\u2010defined four\u2010arm star\u2010shaped polymer. It is further shown that the full dissociation of the star polymer into linear arms via native chemical ligation can easily be followed via size exclusion chromatography, as a result of the change in hydrodynamic volume. Finally, the obtained linear polymers are characterized via matrix\u2010assisted laser desorption\/ionization\u2013time of flight mass spectrometry and found to be in good agreement with the expected molecular weight distribution that confirms the successful transformation.<\/jats:p>","DOI":"10.1002\/marc.201900247","type":"journal-article","created":{"date-parts":[[2019,6,25]],"date-time":"2019-06-25T21:17:26Z","timestamp":1561497446000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Transformation of Thioester\u2010Initiated Star Polymers into Linear Arms via Native Chemical Ligation"],"prefix":"10.1002","volume":"40","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2499-9835","authenticated-orcid":false,"given":"Suzan","family":"Aksakal","sequence":"first","affiliation":[{"name":"School of Engineering and Materials Science Queen Mary University of London  Mile End Road London E1 4NS UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8862-1009","authenticated-orcid":false,"given":"Resat","family":"Aksakal","sequence":"additional","affiliation":[{"name":"School of Engineering and Materials Science Queen Mary University of London  Mile End Road London E1 4NS UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0968-6662","authenticated-orcid":false,"given":"Caglar Remzi","family":"Becer","sequence":"additional","affiliation":[{"name":"School of Engineering and Materials Science Queen Mary University of London  Mile End Road London E1 4NS UK"},{"name":"Department of Chemistry University of Warwick  Coventry CV4 7AL UK"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2019,6,25]]},"reference":[{"key":"e_1_2_4_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200602945"},{"key":"e_1_2_4_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2476"},{"key":"e_1_2_4_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-018-0122"},{"key":"e_1_2_4_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00573G"},{"key":"e_1_2_4_5_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11084-011-9243-4"},{"key":"e_1_2_4_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6PY01721E"},{"key":"e_1_2_4_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-06926-3"},{"key":"e_1_2_4_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7PY00021A"},{"key":"e_1_2_4_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.5b00231"},{"key":"e_1_2_4_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8PY00872H"},{"key":"e_1_2_4_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3py00901g"},{"key":"e_1_2_4_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5PY01916H"},{"key":"e_1_2_4_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00191"},{"key":"e_1_2_4_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/pola.24455"},{"key":"e_1_2_4_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/pola.23042"},{"key":"e_1_2_4_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5PY01623A"},{"key":"e_1_2_4_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6PY01295G"},{"key":"e_1_2_4_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma3001719"},{"key":"e_1_2_4_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma062897b"},{"key":"e_1_2_4_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC05189D"},{"key":"e_1_2_4_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma301034t"},{"key":"e_1_2_4_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b00624"},{"key":"e_1_2_4_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms15655"},{"key":"e_1_2_4_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.biomac.8b00248"},{"key":"e_1_2_4_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/marc.201700500"}],"container-title":["Macromolecular Rapid Communications"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fmarc.201900247","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.201900247","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/marc.201900247","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.201900247","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,10]],"date-time":"2023-09-10T00:00:39Z","timestamp":1694304039000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/marc.201900247"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,6,25]]},"references-count":25,"journal-issue":{"issue":"16","published-print":{"date-parts":[[2019,8]]}},"alternative-id":["10.1002\/marc.201900247"],"URL":"https:\/\/doi.org\/10.1002\/marc.201900247","archive":["Portico"],"relation":{},"ISSN":["1022-1336","1521-3927"],"issn-type":[{"type":"print","value":"1022-1336"},{"type":"electronic","value":"1521-3927"}],"subject":[],"published":{"date-parts":[[2019,6,25]]},"assertion":[{"value":"2019-05-20","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2019-06-25","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"1900247"}}