{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,12]],"date-time":"2026-06-12T20:59:25Z","timestamp":1781297965155,"version":"3.54.1"},"reference-count":33,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2020,2,9]],"date-time":"2020-02-09T00:00:00Z","timestamp":1581206400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21973083"],"award-info":[{"award-number":["21973083"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2020,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Annealing a supported polymer film in the melt state results in the growth of an irreversibly adsorbed layer, which has been shown to influence thin film properties such as diffusion and glass transition temperature. Adsorbed layer growth is attributed to many simultaneous interactions between individual monomer units and the substrate, stabilizing chains against desorption. In this study, adsorbed layers of polystyrene (PS), poly(methyl methacrylate) (PMMA), and their random copolymers are isolated by select solvents. While PS adsorbed layer thickness is largely unaffected by the choice of washing solvent, the PMMA adsorbed layer completely desorbs when washed with tetrahydrofuran and chloroform, as opposed to toluene. Scaling relationships between adsorbed layer thickness and degree of chain adsorption at the substrate enable the use of adsorbed layer thickness to probe specific polymer\u2010substrate interactions. Composition\u2010dependent desorption trends indicate non\u2010preferential adsorption between styrene and methyl methacrylate repeat units at the substrate, despite differences in substrate interaction strength. This insight contributes to the developing mechanism for the adsorption of random copolymers during melt\u2010state annealing, further extending the ability to predict processing\u2010inducted changes to the properties of polymer thin films to heterogeneous systems.<\/jats:p>","DOI":"10.1002\/marc.201900582","type":"journal-article","created":{"date-parts":[[2020,2,10]],"date-time":"2020-02-10T07:08:56Z","timestamp":1581318536000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Revealing Interfacial Interactions in Random Copolymer Adsorbed Layers by Solvent Leaching"],"prefix":"10.1002","volume":"41","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6674-1678","authenticated-orcid":false,"given":"Mary J. B.","family":"Davis","sequence":"first","affiliation":[{"name":"Department of Chemical and Biological Engineering Princeton University  Princeton NJ 08544 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1528-1215","authenticated-orcid":false,"given":"Katelyn","family":"Randazzo","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biological Engineering Princeton University  Princeton NJ 08544 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Biao","family":"Zuo","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biological Engineering Princeton University  Princeton NJ 08544 USA"},{"name":"Department of Chemistry Key Laboratory of Advanced Textile Materials and Manufacturing Technology of the Education Ministry Zhejiang Sci\u2010Tech University  Hangzhou 310018 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6765-2933","authenticated-orcid":false,"given":"Rodney D.","family":"Priestley","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biological Engineering Princeton University  Princeton NJ 08544 USA"},{"name":"Princeton Institute for the Science and Technology of Materials Princeton University  Princeton NJ 08544 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,2,9]]},"reference":[{"key":"e_1_2_5_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aab3896"},{"key":"e_1_2_5_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma401762n"},{"key":"e_1_2_5_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn100464u"},{"key":"e_1_2_5_4_1","doi-asserted-by":"publisher","DOI":"10.1088\/0953-8984\/17\/15\/R01"},{"key":"e_1_2_5_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0001-8686(01)00060-4"},{"key":"e_1_2_5_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/macp.201700368"},{"key":"e_1_2_5_7_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.119.097801"},{"key":"e_1_2_5_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma8027968"},{"key":"e_1_2_5_9_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-319-21948-6"},{"key":"e_1_2_5_10_1","doi-asserted-by":"publisher","DOI":"10.1140\/epje\/i2013-13061-8"},{"key":"e_1_2_5_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms1259"},{"key":"e_1_2_5_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma5003485"},{"key":"e_1_2_5_13_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.109.265501"},{"key":"e_1_2_5_14_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.122.217801"},{"key":"e_1_2_5_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma901851w"},{"key":"e_1_2_5_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.6b00400"},{"key":"e_1_2_5_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.7b00129"},{"key":"e_1_2_5_18_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.107.225901"},{"key":"e_1_2_5_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma502591x"},{"key":"e_1_2_5_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma500506r"},{"key":"e_1_2_5_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/macp.201700303"},{"key":"e_1_2_5_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.7b00473"},{"key":"e_1_2_5_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/mz300432d"},{"key":"e_1_2_5_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8SM01433G"},{"key":"e_1_2_5_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.7b02506"},{"key":"e_1_2_5_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma062864w"},{"key":"e_1_2_5_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.5b02435"},{"key":"e_1_2_5_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma00215a026"},{"key":"e_1_2_5_29_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.70.3267"},{"key":"e_1_2_5_30_1","doi-asserted-by":"publisher","DOI":"10.1201\/9781420006834"},{"key":"e_1_2_5_31_1","unstructured":"THF left a thicker residue after soaking bare substrates likely due to the presence of trace inhibitors. To account for this difference in residue each solvent's residual thickness on blank substrates was subtracted from adsorbed layer thickness measurements to yield the final reported values. Suspected variation in this residue among samples resulted in a few negative adsorbed layer thicknesses in Figure 1."},{"key":"e_1_2_5_32_1","doi-asserted-by":"publisher","DOI":"10.1209\/0295-5075\/17\/3\/007"},{"key":"e_1_2_5_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.8b00240"}],"container-title":["Macromolecular Rapid Communications"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.201900582","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/marc.201900582","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.201900582","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,7]],"date-time":"2023-09-07T14:58:21Z","timestamp":1694098701000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/marc.201900582"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,2,9]]},"references-count":33,"journal-issue":{"issue":"6","published-print":{"date-parts":[[2020,3]]}},"alternative-id":["10.1002\/marc.201900582"],"URL":"https:\/\/doi.org\/10.1002\/marc.201900582","archive":["Portico"],"relation":{},"ISSN":["1022-1336","1521-3927"],"issn-type":[{"value":"1022-1336","type":"print"},{"value":"1521-3927","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,2,9]]},"assertion":[{"value":"2019-11-04","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2020-02-09","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"1900582"}}