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Rapid Commun."],"published-print":{"date-parts":[[2020,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Two sterically congested 2,2\u2032:6\u2032,2\u2033\u2010terpyridine\u2010based ligands LA and LB, composed of asymmetrically contiguous terpyridine units, are designed and synthesized for metallo\u2010supramolecular architectures. The significant advantage of this design is that the terpyridines in these ligands have different chemical environments and show a selective coordination ability with each other. For ditopic ligand LA, the self\u2010assembly with Zn(II), Cd(II), and Fe(II) gave the rhombic dimers, which have the same sets of terpyridine signals as ligand LA. The self\u2010assembly behavior of tritopic ligand LB with Cd(II) and Zn(II) are observed for discrete tetramers under thermodynamic control, whereas ligand LB and Fe(II) are assembled to generate a mixture of tetramer, hexamer, and octamer, which are successfully isolated using regular chromatographic separation. Moreover, the sterically congested ligands and metal ions formed stable intermediates to drive the formation of discrete structures, which is also proved by mixing LB and Cd(II) with a precise stoichiometric ratio of 1:1. These supramolecular complexes are thoroughly characterized by NMR spectroscopy, electrospray ionization\u2010mass spectrometry, and 2D traveling\u2010wave ion mobility\u2010mass spectrometry. This conceptually new design of sterically congested ligands provides a novel strategy for precisely controlled supramolecular complexes with diverse architectures.<\/jats:p>","DOI":"10.1002\/marc.202000095","type":"journal-article","created":{"date-parts":[[2020,4,16]],"date-time":"2020-04-16T07:25:55Z","timestamp":1587021955000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["From Dimeric to Octameric Metallo\u2010Supramolecular Macrocycles Based on Sterically Congested Ligand\u2013assisted Self\u2010Assembly with Zn(II), Cd(II), and Fe(II)"],"prefix":"10.1002","volume":"41","author":[{"given":"Shengwen","family":"Guan","sequence":"first","affiliation":[{"name":"State Key Laboratory of Supramolecular Structure and Materials College of Chemistry Jilin University  Changchun 130012 P. R. 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