{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,24]],"date-time":"2026-07-24T14:04:23Z","timestamp":1784901863164,"version":"3.55.0"},"reference-count":56,"publisher":"Wiley","issue":"24","license":[{"start":{"date-parts":[[2020,5,27]],"date-time":"2020-05-27T00:00:00Z","timestamp":1590537600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21875085"],"award-info":[{"award-number":["21875085"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21373101"],"award-info":[{"award-number":["21373101"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["91027027"],"award-info":[{"award-number":["91027027"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2020,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A novel strategy is reported for the synthesis of glutathione (GSH)\u2010protected bimetallic nanoclusters, Au\u2010AgNCs@GSH, and its fabrication with polyvinyl alcohol (PVA) into a film sensor for H<jats:sub>2<\/jats:sub>S gas detection. Meanwhile, carbon dots (CDs) synthesized from polyethyleneimine (PEI) are introduced as an internal standard to correct the photobleaching of Au\u2010AgNCs@GSH and uniformity of film. The joining of it greatly improves the chemical and structural stability of the composite film via multi cross\u2010linking between PEI, PVA, and GSH. The PVA\u2010AuAgNCs\u2010CDs film exhibits an emission\u2010quenching response to H<jats:sub>2<\/jats:sub>S gas at atmosphere, which is highly repeatable, fast, sensitive, and can distinguish H<jats:sub>2<\/jats:sub>S from other poisonous gases. Finally, the in\u2010depth mechanism investigations reveal that the quenching response is attributed to decomposition of Au\u2010AgNCs@GSH and the formation of Au<jats:sub>2<\/jats:sub>S and Ag<jats:sub>2<\/jats:sub>S in the composite film. As a sensor, the PVA\u2010supported film combines the functions of fluorescent metal nanoclusters and polymer CDs, providing a portable device for the rapid detection of H<jats:sub>2<\/jats:sub>S gas in air.<\/jats:p>","DOI":"10.1002\/marc.202000120","type":"journal-article","created":{"date-parts":[[2020,5,27]],"date-time":"2020-05-27T09:26:49Z","timestamp":1590571609000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["Polyvinyl Alcohol\u2013Supported AuAgNCs\u2010CDs Film as a Selective Sensor for Gas Hydrogen Sulfide Detection in Air"],"prefix":"10.1002","volume":"41","author":[{"given":"Chun\u2010Xia","family":"Zhang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Supramolecular Structure and Materials Institute of Theoretical Chemistry College of Chemistry Jilin University  No. 2699 Qianjin Street Changchun 130012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hong\u2010Wei","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Supramolecular Structure and Materials Institute of Theoretical Chemistry College of Chemistry Jilin University  No. 2699 Qianjin Street Changchun 130012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4883-5982","authenticated-orcid":false,"given":"Yuqing","family":"Wu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Supramolecular Structure and Materials Institute of Theoretical Chemistry College of Chemistry Jilin University  No. 2699 Qianjin Street Changchun 130012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,5,27]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.sna.2013.11.027"},{"key":"e_1_2_7_1_2","first-page":"11868","volume":"15","author":"Tabassum R.","year":"2013","journal-title":"Phys. Chem."},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1111\/j.1471-4159.2010.06580.x"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2009.07.052"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10853-006-0042-7"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm100297q"},{"key":"e_1_2_7_3_3","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2016.08.203"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2015.09.112"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2017.10.128"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.measurement.2011.09.015"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00607D"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.nantod.2016.12.009"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja411643u"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.6b01431"},{"key":"e_1_2_7_8_3","doi-asserted-by":"publisher","DOI":"10.1021\/ac503636j"},{"key":"e_1_2_7_8_4","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00703"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC03086B"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC02280K"},{"key":"e_1_2_7_9_3","doi-asserted-by":"publisher","DOI":"10.1021\/acssensors.8b01130"},{"key":"e_1_2_7_9_4","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.6b05141"},{"key":"e_1_2_7_9_5","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC00702J"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/srep24882"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.talanta.2016.03.066"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C39940000801"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr030063a"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00604-018-3149-z"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1jm13693c"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2nr12056a"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7TC03440G"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.compscitech.2013.02.017"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/am4043799"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.memsci.2014.02.040"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2017.02.022"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.memsci.2007.10.032"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2018.02.072"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9AN00032A"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2019.08.047"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9AN00032A"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5AN00017C"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5AN01378J"},{"key":"e_1_2_7_21_3","doi-asserted-by":"publisher","DOI":"10.1016\/j.bios.2015.12.001"},{"key":"e_1_2_7_21_4","doi-asserted-by":"publisher","DOI":"10.1088\/0957-4484\/27\/42\/425602"},{"key":"e_1_2_7_21_5","doi-asserted-by":"publisher","DOI":"10.1007\/s00604-018-3149-z"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.talanta.2017.04.077"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc36080b"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5b07596"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn501135m"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2015.10.051"},{"key":"e_1_2_7_25_3","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2016.10.134"},{"key":"e_1_2_7_26_1","first-page":"95","volume":"4","author":"Brent Hiskey J.","year":"1988","journal-title":"Extr. Metall. Rev."},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.bios.2013.04.016"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2015.09.112"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2017.10.128"},{"key":"e_1_2_7_28_3","doi-asserted-by":"publisher","DOI":"10.1016\/j.measurement.2011.09.015"},{"key":"e_1_2_7_28_4","doi-asserted-by":"publisher","DOI":"10.1038\/srep24882"},{"key":"e_1_2_7_28_5","doi-asserted-by":"publisher","DOI":"10.1016\/j.talanta.2016.03.066"}],"container-title":["Macromolecular Rapid Communications"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fmarc.202000120","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.202000120","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/marc.202000120","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.202000120","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,3]],"date-time":"2023-09-03T06:30:03Z","timestamp":1693722603000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/marc.202000120"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,5,27]]},"references-count":56,"journal-issue":{"issue":"24","published-print":{"date-parts":[[2020,12]]}},"alternative-id":["10.1002\/marc.202000120"],"URL":"https:\/\/doi.org\/10.1002\/marc.202000120","archive":["Portico"],"relation":{},"ISSN":["1022-1336","1521-3927"],"issn-type":[{"value":"1022-1336","type":"print"},{"value":"1521-3927","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,5,27]]},"assertion":[{"value":"2020-03-08","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2020-05-27","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2000120"}}