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Rapid Commun."],"published-print":{"date-parts":[[2020,6]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>As an important nitrogen source, isocyanides have been involved in numerous organic reactions. As a result, many complicated compounds have been successfully synthesized through isocyanide chemistry. However, compared with its popular research in organic reactions, the application of isocyanides in polymerization is less investigated. In this work, a new polymerization based on isocyanide monomers is established. By simply mixing diisocyanoacetates and dialdehydes in the presence of a catalytic system of CuCl\/PPh<jats:sub>3<\/jats:sub>\/organobase in dichloromethane at room temperature readily produces soluble and thermally stable oxazoline\u2010containing polymers with moderate weight\u2010averaged molecular weights (<jats:italic>M<\/jats:italic><jats:sub>w<\/jats:sub> up to 11\u2009200) in excellent yields (up to 97%) after 6 h. Furthermore, introducing the tetraphenylethene moiety into the main chains endows the resultant polymers with aggregation\u2010induced emission, which can function as fluorescent probes for Fe<jats:sup>3+<\/jats:sup> ion detection with high sensitivity and selectivity. This work not only enriches the family of isocyanide\u2010based polymerizations but also provides an efficient tool for the preparation of functional heterocycle\u2010containing polymers.<\/jats:p>","DOI":"10.1002\/marc.202000179","type":"journal-article","created":{"date-parts":[[2020,5,28]],"date-time":"2020-05-28T12:32:50Z","timestamp":1590669170000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Isocyanoacetate\u2010Aldehyde Polymerization: A Facile Tool toward Functional Oxazoline\u2010Containing Polymers"],"prefix":"10.1002","volume":"41","author":[{"given":"Tianyu","family":"Cheng","sequence":"first","affiliation":[{"name":"State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates Center for Aggregation\u2010Induced Emission South China University of Technology  Guangzhou 510640 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Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates Center for Aggregation\u2010Induced Emission South China University of Technology  Guangzhou 510640 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ben Zhong","family":"Tang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates Center for Aggregation\u2010Induced Emission South China University of Technology  Guangzhou 510640 China"},{"name":"Department of Chemistry Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction Institute for Advanced Study Department of Chemical and Biological Engineering The Hong Kong University of Science &amp; Technology Clear Water Bay  Kowloon Hong Kong China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2020,5,28]]},"reference":[{"key":"e_1_2_5_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.196200081"},{"key":"e_1_2_5_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20000915)39:18<3168::AID-ANIE3168>3.0.CO;2-U"},{"key":"e_1_2_5_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20000915)6:18<3321::AID-CHEM3321>3.0.CO;2-A"},{"key":"e_1_2_5_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200390167"},{"key":"e_1_2_5_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar020258p"},{"key":"e_1_2_5_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr0505728"},{"key":"e_1_2_5_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2008.12.002"},{"key":"e_1_2_5_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr500380d"},{"key":"e_1_2_5_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201000723"},{"key":"e_1_2_5_10_1","doi-asserted-by":"publisher","DOI":"10.1007\/b95531"},{"key":"e_1_2_5_11_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426-018-9415-8"},{"key":"e_1_2_5_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr990126i"},{"key":"e_1_2_5_13_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10118-017-2003-9"},{"key":"e_1_2_5_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5PY02030A"},{"key":"e_1_2_5_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4PY01147C"},{"key":"e_1_2_5_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4PY00001C"},{"key":"e_1_2_5_17_1","doi-asserted-by":"publisher","DOI":"10.1007\/12_2014_298"},{"key":"e_1_2_5_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/mz300456p"},{"key":"e_1_2_5_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201305538"},{"key":"e_1_2_5_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma500504w"},{"key":"e_1_2_5_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr900411f"},{"key":"e_1_2_5_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.8b01179"},{"key":"e_1_2_5_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr900149d"},{"key":"e_1_2_5_24_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426-019-9517-9"},{"key":"e_1_2_5_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/b909064a"},{"key":"e_1_2_5_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2017.09.004"},{"key":"e_1_2_5_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma062859s"},{"key":"e_1_2_5_28_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426-019-9465-7"},{"key":"e_1_2_5_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma800538m"},{"key":"e_1_2_5_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.200801933"},{"key":"e_1_2_5_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5PY00186B"},{"key":"e_1_2_5_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b00929"},{"key":"e_1_2_5_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7PY00363C"},{"key":"e_1_2_5_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201702966"},{"key":"e_1_2_5_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo00821a011"},{"key":"e_1_2_5_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)98925-1"},{"key":"e_1_2_5_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2006.10.040"},{"key":"e_1_2_5_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja110534g"},{"key":"e_1_2_5_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.6b04827"},{"key":"e_1_2_5_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/macp.201400571"},{"key":"e_1_2_5_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/b105159h"},{"key":"e_1_2_5_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00263"},{"key":"e_1_2_5_43_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10118-019-2221-4"},{"key":"e_1_2_5_44_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8QM00062J"},{"key":"e_1_2_5_45_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1107224"},{"key":"e_1_2_5_46_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.287.5453.655"},{"key":"e_1_2_5_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr9001676"},{"key":"e_1_2_5_48_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11064-009-0100-z"},{"key":"e_1_2_5_49_1","doi-asserted-by":"publisher","DOI":"10.1038\/sj.bjp.0706416"},{"key":"e_1_2_5_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr900223a"},{"key":"e_1_2_5_51_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs35152h"},{"key":"e_1_2_5_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.6b00065"},{"key":"e_1_2_5_53_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1nj20122k"},{"key":"e_1_2_5_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2016.11.003"},{"key":"e_1_2_5_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.7b00992"},{"key":"e_1_2_5_56_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC05173H"}],"container-title":["Macromolecular 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