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A set of monomers with varying electron densities, fine\u2010tuned by different substituents on the aromatic sulfonamide moiety, is polymerized by free radical polymerization featuring low molar masses (2300\u00a0\u00a0\u2264\u00a0<jats:italic>M<\/jats:italic><jats:sub>n<\/jats:sub>\u00a0\u2264\u00a03200\u00a0g\u00a0mol<jats:sup>\u22121<\/jats:sup>) and low dispersities (1.15\u00a0\u2264\u00a0<jats:italic>\u0110<\/jats:italic>\u00a0\u2264\u00a01.47). Further, the post\u2010polymerization modification of the obtained polymers via aza\u2010Michael addition with electron\u2010deficient alkenes is demonstrated using organic superbases as catalysts, paving the way toward the facile synthesis of novel polymeric protected \u03b2\u2010amino acid derivatives.<\/jats:p>","DOI":"10.1002\/marc.202100063","type":"journal-article","created":{"date-parts":[[2021,5,3]],"date-time":"2021-05-03T16:58:11Z","timestamp":1620061091000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Synthesis and Post\u2010Polymerization Modification of Poly(<i>N<\/i>\u2010(4\u2010Vinylphenyl)Sulfonamide)s"],"prefix":"10.1002","volume":"42","author":[{"given":"Edgar","family":"Molle","sequence":"first","affiliation":[{"name":"Institute for Chemical Technology and Polymer Chemistry (ITCP) Karlsruhe Institute of Technology (KIT)  Engesserstr. 18 76131 Karlsruhe 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