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Rapid Commun."],"published-print":{"date-parts":[[2021,7]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>In this communication, the preparation of crosslinked polydicyclopentadiene (PDCPD) nanoparticles via ring\u2010opening metathesis polymerization (ROMP)\u2010induced self\u2010assembly approach is reported. For the ROMPs, the macromolecular chain transfer agents (Macro\u2010CTAs) are synthesized via the ring\u2010opening polymerization (ROP) of <jats:italic>\u03b5<\/jats:italic>\u2010caprolactone (CL) with <jats:italic>cis<\/jats:italic>\u20102\u2010butene\u20101,4\u2010diol as the initiator. The ROMPs are performed with chloroform, tetrahydrofuran, toluene, 1,4\u2010dioxane, and <jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2010dimethylacetamide as the solvents, respectively, which are catalyzed with Grubbs second generation catalyst. It is found that the crosslinked PDCPD nanoparticles are obtained with spherical, cylindrical to planar morphologies, depending on the molecular weights of Macro\u2010CTAs, the concentrations of DCPD and the natures of solvents. The polymerization induced self\u2010assembly (ROMPISA) by the use of a non\u2010norbornene\u2010based macromolecular chain transfer agent provides a new and efficient approach to prepare crosslinked polymer nanoparticles.<\/jats:p>","DOI":"10.1002\/marc.202100155","type":"journal-article","created":{"date-parts":[[2021,5,31]],"date-time":"2021-05-31T10:50:27Z","timestamp":1622458227000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Crosslinked Polydicyclopentadiene Nanoparticles via Ring\u2010Opening Metathesis Polymerization\u2010Induced Self\u2010Assembly Approach"],"prefix":"10.1002","volume":"42","author":[{"given":"Honggang","family":"Mei","sequence":"first","affiliation":[{"name":"College of Chemistry and Chemical Engineering and the State Key Laboratory of Metal Matrix Composites Shanghai Jiao Tong University  Shanghai 200240 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bingjie","family":"Zhao","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering and the State Key Laboratory of Metal Matrix Composites Shanghai Jiao Tong University  Shanghai 200240 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Huaming","family":"Wang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering and the State Key Laboratory of Metal Matrix Composites Shanghai Jiao Tong University  Shanghai 200240 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2003-8754","authenticated-orcid":false,"given":"Sixun","family":"Zheng","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering and the State Key Laboratory of Metal Matrix Composites Shanghai Jiao Tong University  Shanghai 200240 P. R. 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