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Rapid Commun."],"published-print":{"date-parts":[[2022,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>3D pyramidal polymer single crystals provide spatial gradient variations within the crystal molecules, and these variations facilitate the study of the relationship between structure and properties within the molecules of various complexes with anisotropic structures. As described herein, a low\u2010temperature\u2010assisted microfluidic pore channeling approach is proposed to prepare structurally ordered polymer single crystals. A mixture of dichloromethane and dimethyl sulfoxide is used as a prepolymer, and a liquid microfluidic technique is employed to grow the end\u2010functionalized polymers into 3D polymer single crystals. Through the ordered growth of single crystals, a personalized pyramidal pattern with a homogeneous structure is formed. To evaluate the mesh node density, low\u2010temperature growth time and substrate type are also investigated. Rectangular, pyramidal, and dendritic patterns are synthesized via low\u2010temperature single crystal growth. This work shows that low temperature\u2010assisted microfluidics provides a novel means to tune the 3D structure of polymer single crystals.<\/jats:p>","DOI":"10.1002\/marc.202100747","type":"journal-article","created":{"date-parts":[[2021,12,30]],"date-time":"2021-12-30T11:23:21Z","timestamp":1640863401000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Terraced and 3D Pyramid\u2010Shaped Polymer Single Crystal via Low Temperature\u2010Assisted Microfluidic Technology"],"prefix":"10.1002","volume":"43","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4780-2863","authenticated-orcid":false,"given":"Shi","family":"Li","sequence":"first","affiliation":[{"name":"Guangzhou Institute of Chemistry Chinese Academy of Sciences  Guangzhou 510650 P. R. 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