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Rapid Commun."],"published-print":{"date-parts":[[2023,7]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Volatile organic compounds (VOCs) may have short\u2010 and long\u2010term adverse health effects. Especially, aromatic VOCs including benzene, toluene, ethylbenzene, and xylene (BTEX) are important indoor air pollutants. Developing highly efficient porous adsorbents with broad applicability remains a major challenge. In this study, a perchlorinated covalent\u2010triazine framework (ClCTF\u20101\u2010400) is prepared for adsorbing BTEX. ClCTF\u20101\u2010400 is confirmed as a partially oxidized\/chlorinated microporous covalent triazine framework through a variety of characterization. It is found that ClCTF\u20101\u2010400 is reversible VOCs absorbent with very high absorption capacities, which can adsorb benzene (693\u00a0mg g<jats:sup>\u22121<\/jats:sup>), toluene (621\u00a0mg g<jats:sup>\u22121<\/jats:sup>), ethylbenzene (603\u00a0mg g<jats:sup>\u22121<\/jats:sup>), <jats:italic>o<\/jats:italic>\u2010xylene (500\u00a0mg g<jats:sup>\u22121<\/jats:sup>), <jats:italic>m<\/jats:italic>\u2010xylene (538\u00a0mg g<jats:sup>\u22121<\/jats:sup>), and <jats:italic>p<\/jats:italic>\u2010xylene (592\u00a0mg g<jats:sup>\u22121<\/jats:sup>) at 25 \u00b0C and their saturated vapor pressure (\u2248 1\u00a0kPa). ClCTF\u20101\u2010400 is of higher adsorption capacities for all selected VOCs than activated carbon and other reported adsorbents. The adsorption mechanism is also inferred through theoretical calculation and in\u2010site Fourier Transform Infrared (FTIR) spectroscopy. The observed excellent BTEX adsorption performance is attributed to the multiple weak interactions between the ClCTF\u20101\u2010400 frameworks and aromatic molecules through multiple weak interactions (C\uf8ffH<jats:sup>\u2026<\/jats:sup><jats:italic>\u03c0<\/jats:italic> and C\uf8ffCl<jats:sup>\u2026<\/jats:sup><jats:italic>\u03c0<\/jats:italic>). The breakthrough experiment demonstrates ClCTF\u20101\u2010400 has the potential for real VOCs pollutant removal in air.<\/jats:p>","DOI":"10.1002\/marc.202200974","type":"journal-article","created":{"date-parts":[[2023,5,8]],"date-time":"2023-05-08T08:03:17Z","timestamp":1683532997000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Enhanced Adsorption of Aromatic Volatile Organic Compounds on a Perchloro Covalent Triazine Framework through Multiple Intermolecular Interactions"],"prefix":"10.1002","volume":"44","author":[{"given":"Shuyue","family":"Wen","sequence":"first","affiliation":[{"name":"Tianjin Key Laboratory of Advanced Functional Porous Materials, School of Materials Science and Engineering Tianjin University of Technology  Tianjin 300384 China"},{"name":"Key Laboratory of Mesoscopic Chemistry of MOE School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210023 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