{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T21:10:54Z","timestamp":1792098654369,"version":"4.4.0"},"reference-count":90,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2024,5,10]],"date-time":"2024-05-10T00:00:00Z","timestamp":1715299200000},"content-version":"am","delay-in-days":356,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#am"},{"start":{"date-parts":[[2023,5,20]],"date-time":"2023-05-20T00:00:00Z","timestamp":1684540800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["DMR\u20101904631"],"award-info":[{"award-number":["DMR\u20101904631"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["EEC\u20101941529"],"award-info":[{"award-number":["EEC\u20101941529"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100017325","name":"Engineering Research Centers","doi-asserted-by":"publisher","award":["1941529"],"award-info":[{"award-number":["1941529"]}],"id":[{"id":"10.13039\/100017325","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000078","name":"Division of Materials Research","doi-asserted-by":"publisher","award":["1904631"],"award-info":[{"award-number":["1904631"]}],"id":[{"id":"10.13039\/100000078","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2023,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Poly(vinyl ketones) (PVKs) have received considerable attention over the past few decades due to their unique photochemistry and photodegradation properties under ultraviolet (UV) light. Many PVKs rapidly undergo photodegradation under UV light. The side\u2010chain carbonyl moieties of PVKs permit photolysis through Norrish type I or Norrish type II reaction mechanisms and can also be readily modified by nucleophilic addition reactions. These unique properties lead to this class of polymers serving as versatile scaffolds for generating functional materials. This review captures the evolution of synthetic routes to access well\u2010defined PVKs, along with their photochemistry and photo\u2010degradation pathways, and discusses recent and potential applications of these photodegradable materials.<\/jats:p>","DOI":"10.1002\/marc.202300126","type":"journal-article","created":{"date-parts":[[2023,5,11]],"date-time":"2023-05-11T05:09:08Z","timestamp":1683781748000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":25,"title":["Poly(Vinyl Ketones): New Directions in Photodegradable Polymers"],"prefix":"10.1002","volume":"44","author":[{"given":"Digvijayee","family":"Pal","sequence":"first","affiliation":[{"name":"George &amp; Josephine Butler Polymer Research Laboratory, Center for Macromolecular Science &amp; Engineering, Department of Chemistry University of Florida  P.O. Box 117200 Gainesville FL 32611 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Debabrata","family":"Konar","sequence":"additional","affiliation":[{"name":"George &amp; Josephine Butler Polymer Research Laboratory, Center for Macromolecular Science &amp; Engineering, Department of Chemistry University of Florida  P.O. Box 117200 Gainesville FL 32611 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5749-5444","authenticated-orcid":false,"given":"Brent S.","family":"Sumerlin","sequence":"additional","affiliation":[{"name":"George &amp; Josephine Butler Polymer Research Laboratory, Center for Macromolecular Science &amp; Engineering, Department of Chemistry University of Florida  P.O. Box 117200 Gainesville FL 32611 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,5,20]]},"reference":[{"key":"e_1_2_10_1_1","unstructured":"Plastics: The Facts 2015 http:\/\/www.plasticseurope.org\/Document\/plastics\u2014the\u2010facts\u20102015.aspx(accessed: August 2017)."},{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.1557\/mrs.2011.210"},{"key":"e_1_2_10_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00329"},{"key":"e_1_2_10_4_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1260352"},{"key":"e_1_2_10_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/2014EF000240"},{"key":"e_1_2_10_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma961327g"},{"key":"e_1_2_10_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-17542-5"},{"key":"e_1_2_10_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c01768"},{"key":"e_1_2_10_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.addr.2016.03.010"},{"key":"e_1_2_10_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/cptc.201900166"},{"key":"e_1_2_10_11_1","doi-asserted-by":"publisher","DOI":"10.1080\/17518250903506723"},{"key":"e_1_2_10_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/masy.19971230121"},{"key":"e_1_2_10_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja073541y"},{"key":"e_1_2_10_14_1","first-page":"87","volume":"31","author":"Sugita K.","year":"1997","journal-title":"Prog. Phys. Org. Chem."},{"key":"e_1_2_10_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja039203o"},{"key":"e_1_2_10_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.0c00401"},{"key":"e_1_2_10_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja060276s"},{"key":"e_1_2_10_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1PY00781E"},{"key":"e_1_2_10_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.6b01609"},{"key":"e_1_2_10_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.2c00603"},{"key":"e_1_2_10_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2PY01383E"},{"key":"e_1_2_10_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202209085"},{"key":"e_1_2_10_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.2c00091"},{"key":"e_1_2_10_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1PY01643A"},{"key":"e_1_2_10_25_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-94-017-1217-0"},{"key":"e_1_2_10_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja01269a016"},{"key":"e_1_2_10_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/0014-3057(71)90049-8"},{"key":"e_1_2_10_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.1983.070280329"},{"key":"e_1_2_10_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3765(19980807)4:8<1411::AID-CHEM1411>3.0.CO;2-E"},{"key":"e_1_2_10_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/pol.1972.230060104"},{"key":"e_1_2_10_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma60026a021"},{"key":"e_1_2_10_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma60032a016"},{"key":"e_1_2_10_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/0141-3910(80)90006-3"},{"key":"e_1_2_10_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1097-4628(19991107)74:6<1432::AID-APP16>3.0.CO;2-Z"},{"key":"e_1_2_10_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma60073a036"},{"key":"e_1_2_10_36_1","volume-title":"Controlled\/Living Radical Polymerization, Handbook of Polymer Synthesis","author":"Matyjaszewski K.","year":"2004"},{"key":"e_1_2_10_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/mren.200900087"},{"key":"e_1_2_10_38_1","doi-asserted-by":"crossref","first-page":"277","DOI":"10.1021\/bk-2012-1100","volume-title":"Progress in Controlled Radical Polymerization: Mechanism and Techniques, ACS Symposium Series 1100","author":"Matyjaszewski K.","year":"2012"},{"key":"e_1_2_10_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.5b00342"},{"key":"e_1_2_10_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma060365p"},{"key":"e_1_2_10_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/pola.25997"},{"key":"e_1_2_10_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma9804951"},{"key":"e_1_2_10_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60290G"},{"key":"e_1_2_10_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.7b00767"},{"key":"e_1_2_10_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/marc.201900302"},{"key":"e_1_2_10_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/marc.201600623"},{"key":"e_1_2_10_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/cptc.201900052"},{"key":"e_1_2_10_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja501745g"},{"key":"e_1_2_10_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.8b01600"},{"key":"e_1_2_10_50_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7PY00617A"},{"key":"e_1_2_10_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200907163"},{"key":"e_1_2_10_52_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC06254G"},{"key":"e_1_2_10_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/cptc.201900044"},{"key":"e_1_2_10_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma202673q"},{"key":"e_1_2_10_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma00153a043"},{"key":"e_1_2_10_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/apmc.1978.050710111"},{"key":"e_1_2_10_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/pol.1977.170151107"},{"key":"e_1_2_10_58_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5RA02863A"},{"key":"e_1_2_10_59_1","doi-asserted-by":"publisher","DOI":"10.1080\/15421406.2017.1355215"},{"key":"e_1_2_10_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099-0518(199608)34:11<2181::AID-POLA11>3.0.CO;2-B"},{"key":"e_1_2_10_61_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma60068a042"},{"key":"e_1_2_10_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac060311d"},{"key":"e_1_2_10_63_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma60046a009"},{"key":"e_1_2_10_64_1","doi-asserted-by":"publisher","DOI":"10.1016\/0032-3861(81)90267-6"},{"key":"e_1_2_10_65_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.1993.070490417"},{"key":"e_1_2_10_66_1","doi-asserted-by":"publisher","DOI":"10.1002\/macp.1979.021800321"},{"key":"e_1_2_10_67_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF00282286"},{"key":"e_1_2_10_68_1","doi-asserted-by":"publisher","DOI":"10.1515\/pac-2014-0803"},{"key":"e_1_2_10_69_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00449-016-1566-0"},{"key":"e_1_2_10_70_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules25010049"},{"key":"e_1_2_10_71_1","doi-asserted-by":"publisher","DOI":"10.1006\/jsbi.1999.4104"},{"key":"e_1_2_10_72_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2007.05.054"},{"key":"e_1_2_10_73_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00216-005-3334-x"},{"key":"e_1_2_10_74_1","doi-asserted-by":"publisher","DOI":"10.1002\/pola.26790"},{"key":"e_1_2_10_75_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma00003a007"},{"key":"e_1_2_10_76_1","first-page":"17","volume":"1","author":"Kaur R.","year":"2017","journal-title":"Chem"},{"key":"e_1_2_10_77_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma00049a014"},{"key":"e_1_2_10_78_1","doi-asserted-by":"publisher","DOI":"10.1080\/15685551.2018.1521563"},{"key":"e_1_2_10_79_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.7b00465"},{"key":"e_1_2_10_80_1","doi-asserted-by":"publisher","DOI":"10.1002\/pola.10860"},{"key":"e_1_2_10_81_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.1984.070290525"},{"key":"e_1_2_10_82_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.1985.070300416"},{"key":"e_1_2_10_83_1","doi-asserted-by":"publisher","DOI":"10.1080\/10601329008544813"},{"key":"e_1_2_10_84_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7PY01945A"},{"key":"e_1_2_10_85_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.reactfunctpolym.2011.05.003"},{"key":"e_1_2_10_86_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40242-015-4440-8"},{"key":"e_1_2_10_87_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.6b04774"},{"key":"e_1_2_10_88_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp072136q"},{"key":"e_1_2_10_89_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.2c00683"},{"key":"e_1_2_10_90_1","doi-asserted-by":"publisher","DOI":"10.1351\/pac197749030249"}],"container-title":["Macromolecular Rapid Communications"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/am-pdf\/10.1002\/marc.202300126","content-type":"application\/pdf","content-version":"am","intended-application":"syndication"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.202300126","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,8,17]],"date-time":"2023-08-17T17:46:11Z","timestamp":1692294371000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/marc.202300126"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,5,20]]},"references-count":90,"journal-issue":{"issue":"15","published-print":{"date-parts":[[2023,8]]}},"alternative-id":["10.1002\/marc.202300126"],"URL":"https:\/\/doi.org\/10.1002\/marc.202300126","archive":["Portico"],"relation":{},"ISSN":["1022-1336","1521-3927"],"issn-type":[{"value":"1022-1336","type":"print"},{"value":"1521-3927","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,5,20]]},"assertion":[{"value":"2023-03-08","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2023-05-20","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2300126"}}