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The acrylamide copolymers are prepared under light irradiation at 405\u00a0nm and thermal post\u2010curing processes. Low molecular weight poly(ethylene glycol)diacrylate (PEGDA) and <jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2010dimethylacrylamide (DMAM), both liquid resins, are used as co\u2010monomers and diluents for the amino acid\u2010derived acrylamide solubilization. The presence of two phenylalanine units and two ester groups in the acrylamide monomer accuses a fast degradation rate in hydrolytic medium in 90 days. The residual products leached in the aqueous media prove to be non\u2010cytotoxic, when 3D\u2010printed samples are cultured with osteoblast cells (MG63), which represents an advantage for the safe disposal of printer waste materials. The scaled\u2010up pieces derived from <jats:sc>l<\/jats:sc>\u2010phenylalanine and diethylene glycol, as amino acid\u2010derived acrylamide (named compound <jats:bold>C<\/jats:bold>), PEGDA and DMAM, present high dimensional stability after DLP printing of complex structures used as testing samples. Layers of 50\u00a0\u00b5m of thickness are well cohesive having isotropic behavior, as demonstrated with tensile\u2010strain measurements performed in <jats:italic>X<\/jats:italic>\u2013<jats:italic>Y<\/jats:italic>\u2013<jats:italic>Z<\/jats:italic> (plane) directions. The compound <jats:bold>C<\/jats:bold>, which contains phenylalanine amino acid, reveals a promising potential to replace non\u2010biodegradable acrylate polymers used in prototyping systems.<\/jats:p>","DOI":"10.1002\/marc.202300132","type":"journal-article","created":{"date-parts":[[2023,5,16]],"date-time":"2023-05-16T10:05:52Z","timestamp":1684231552000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Digital Light Processing\u20103D Printing of Thermoset Materials with High Biodegradability from Amino Acid\u2010Derived Acrylamide Monomers"],"prefix":"10.1002","volume":"44","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4387-4595","authenticated-orcid":false,"given":"Isaac","family":"Isarn","sequence":"first","affiliation":[{"name":"ICIQ\u2010CERCA\u2013Institute of Chemical Research of Catalonia The Barcelona Institute of Science and Technology  Avinguda dels Pa\u00efsos Catalans 16 Tarragona 43007 Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5113-4610","authenticated-orcid":false,"given":"\u013dudmila","family":"Hod\u00e1sov\u00e1","sequence":"additional","affiliation":[{"name":"IMEM\u2010BRT Group, Departament d'Enginyeria Qu\u00edmica, EEBE Universitat Polit\u00e8cnica de Catalunya  C\/Eduard Maristany, 10\u201314, Ed. 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