{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T20:17:56Z","timestamp":1789589876426,"version":"build-2803163510"},"reference-count":34,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2023,7,19]],"date-time":"2023-07-19T00:00:00Z","timestamp":1689724800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001711","name":"Schweizerischer Nationalfonds zur F\u00f6rderung der Wissenschaftlichen Forschung","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001711","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2023,9]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A new heterocyclic monomer is developed via simple Diels\u2013Alder reaction which is reluctant to polymerize in dichloromethane (DCM) whereas undergoes facile polymerization in tetrahydrofuran with excellent control over molecular weight (<jats:italic>M<jats:sub>n<\/jats:sub><\/jats:italic>) and dispersities (<jats:italic>\u0110<\/jats:italic>) using Grubbs' third generation catalyst (G3). The deprotection of the <jats:italic>tert<\/jats:italic>\u2010butoxycarbonyl group from the polymeric backbone yielded a water\u2010soluble ring opening metathesis polymerization (ROMP) polymer easily. Moreover, in DCM this new monomer copolymerizes with 2,3\u2010dihydrofuran under catalytic living ROMP conditions to give backbone degradable polymers. All the synthesized polymers are characterized by size exclusion chromatography (SEC) and nuclear magnetic resonance (NMR) spectroscopy. It is believed that this new route to water soluble ROMP homopolymers as well as the cost\u2010effective and environmentally friendly route to degradable copolymers and block\u2010copolymers could find applications in biomedicine in the near future.<\/jats:p>","DOI":"10.1002\/marc.202300218","type":"journal-article","created":{"date-parts":[[2023,7,12]],"date-time":"2023-07-12T12:24:18Z","timestamp":1689164658000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Controlled Ring Opening Metathesis Polymerization of a New Monomer: On Switching the Solvent\u2014Water\u2010Soluble Homopolymers to Degradable Copolymers"],"prefix":"10.1002","volume":"44","author":[{"given":"Ankita","family":"Mandal","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Fribourg  Fribourg CH\u20101700 Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Subhajit","family":"Pal","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Fribourg  Fribourg CH\u20101700 Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2929-7499","authenticated-orcid":false,"given":"Andreas F. M.","family":"Kilbinger","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Fribourg  Fribourg CH\u20101700 Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,7,19]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1163\/156856293X00537"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1042\/BST0350056"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym3041972"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym4020913"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/pola.22950"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym11020298"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2006.08.006"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/9783527619481"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.polymer.2010.05.002"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/pj.2010.94"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201806719"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c05499"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja801662y"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/pola.23098"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs15348c"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200250632"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00027A"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1359-6446(01)01757-3"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tibtech.2005.07.010"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol102270r"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC00036E"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-019-0239-4"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-021-00810-2"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c06045"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202211842"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.0c00427"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b03665"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202203344"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja204309d"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja801919y"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/om301192a"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.2c01373"},{"key":"e_1_2_7_33_1","first-page":"5422","volume":"12","author":"Mandal A.","year":"2023","journal-title":"Polym. Chem."},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b11834"}],"container-title":["Macromolecular Rapid Communications"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.202300218","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,21]],"date-time":"2023-09-21T03:45:50Z","timestamp":1695267950000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/marc.202300218"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,7,19]]},"references-count":34,"journal-issue":{"issue":"18","published-print":{"date-parts":[[2023,9]]}},"alternative-id":["10.1002\/marc.202300218"],"URL":"https:\/\/doi.org\/10.1002\/marc.202300218","archive":["Portico"],"relation":{},"ISSN":["1022-1336","1521-3927"],"issn-type":[{"value":"1022-1336","type":"print"},{"value":"1521-3927","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,7,19]]},"assertion":[{"value":"2023-04-19","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2023-07-19","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2300218"}}