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Rapid Commun."],"published-print":{"date-parts":[[2023,10]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Over the past decade, polymerization\u2010induced self\u2010assembly (PISA) has fully proved its versatility for scale\u2010up production of block copolymer nanoparticles with tunable sizes and morphologies; yet, there are still some limitations. Recently, seeded PISA approaches combing PISA with heterogeneous seeded polymerizations have been greatly explored and are expected to overcome the limitations of traditional PISA. In this review, recent advances in seeded PISA that have expanded new horizons for PISA are highlighted including i) general considerations for seeded PISA (e.g., kinetics, the preparation of seeds, the selection of monomers), ii) morphological evolution induced by seeded PISA (e.g., from corona\u2010shell\u2010core nanoparticles to vesicles, vesicles\u2010to\u2010toroid, disassembly of vesicles into nanospheres), and iii) various well\u2010defined nanoparticles with hierarchical and sophisticated morphologies (e.g., multicompartment micelles, porous vesicles, framboidal vesicles, AX<jats:sub>n<\/jats:sub>\u2010type colloidal molecules). Finally, new insights into seeded PISA and future perspectives are proposed.<\/jats:p>","DOI":"10.1002\/marc.202300334","type":"journal-article","created":{"date-parts":[[2023,8,24]],"date-time":"2023-08-24T14:03:54Z","timestamp":1692885834000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Seeded RAFT Polymerization\u2010Induced Self\u2010assembly: Recent Advances and Future Opportunities"],"prefix":"10.1002","volume":"44","author":[{"given":"Yifei","family":"Chen","sequence":"first","affiliation":[{"name":"State Key Laboratory of Ophthalmology Optometry and Vision Science School of Ophthalmology and Optometry Eye Hospital School of Biomedical Engineering Wenzhou Medical University  Wenzhou 325027 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