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Rapid Commun."],"published-print":{"date-parts":[[2023,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Crosslinking chemistries occupy an important position in polymer modification with a particular importance when triggered in response to external stimuli. Enediyne (EDY) moieties are used as functional entities in this work, known to undergo a pericyclic Bergman cyclization (BC) to induce a triggered crosslinking of polyurethanes (PU) via the intermediately formed diradicals. Diamino\u2010EDYs, where the distance between the enyne\u2010moieties is known to be critical to induce a BC, are placed repetitively as main\u2010chain structural elements in isophorone\u2010based PUs to induce reinforcement upon heating, compression, or stretching. A 7\u2010day compression under room temperature results in a \u224869% activation of the BC, together with the observation of an increase in tensile strength by 62% after 25 stretching cycles. The occurrence of BC is further proven by the decreased exothermic values in differential scanning calorimetry, together with characteristic peaks of the formed benzene moieties via IR spectroscopy. Purely heat\u2010induced crosslinking contributes to 191% of the maximum tensile strength in comparison to the virgin PU. The BC herein forms an excellent crosslinking strategy, triggered by heat or force in PU materials.<\/jats:p>","DOI":"10.1002\/marc.202300440","type":"journal-article","created":{"date-parts":[[2023,10,25]],"date-time":"2023-10-25T11:26:01Z","timestamp":1698233161000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Triggered Crosslinking of Main\u2010Chain Enediyne Polyurethanes via Bergman Cyclization"],"prefix":"10.1002","volume":"44","author":[{"given":"Yue","family":"Cai","sequence":"first","affiliation":[{"name":"Macromolecular Chemistry Institute of Chemistry Faculty of Natural Science II Martin Luther University Halle\u2010Wittenberg  Von\u2010Danckelmann\u2010Platz 4 06120 Halle (Saale) Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3834-5445","authenticated-orcid":false,"given":"Wolfgang 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