{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,10]],"date-time":"2026-03-10T02:13:52Z","timestamp":1773108832082,"version":"3.50.1"},"reference-count":39,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2023,11,29]],"date-time":"2023-11-29T00:00:00Z","timestamp":1701216000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2024,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Catalytic hydrosilylation is one of the important synthetic approaches to prepare functional organosilicon polymers. Herein, a functional silicon copolymer is constructed by polyhydrosilylation reaction between a novel 3,7\u2010bis(dimethyl silane)\u201010\u2010(2\u2010ethylhexyl)\u201010<jats:italic>H<\/jats:italic>\u2010phenothiazine monomer and a neutral tetrapyrrolic macrocycle, namely, 5,5,10,15,15,20\u2010hexamethyl\u201010\u03b1, 20\u03b1\u2010bis(4\u2010[ethynylphenyl]) calix[4]pyrrole. The as\u2010constructed copolymer (<jats:italic>M<\/jats:italic><jats:sub>n<\/jats:sub>\u00a0=\u00a09609, PDI\u00a0=\u00a02.2) is investigated as an extractant for organic anions as their tetrabutylammonium salts under interfacial aqueous\u2010organic (water\u2010chloroform) conditions. In this context, a distinctive naked\u2010eye colorimetric as well as fluorescence detection method is developed based on anion\u2010directed hydrogen\u2010bonding interactions. This kind of color\/fluorescence monitoring serves as a handy tool for rapid screening of anion extraction processes. The copolymer exhibits high selectivity toward extraction of chloride anion. This study augments the field of polycarbosilanes, poly(silylenevinylene)s in particular, allowing access to a new application window that can be further advanced with good grace in near future.<\/jats:p>","DOI":"10.1002\/marc.202300527","type":"journal-article","created":{"date-parts":[[2023,11,22]],"date-time":"2023-11-22T13:51:23Z","timestamp":1700661083000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["A Heteroatom\u2010Containing Functional Poly(Silylenevinylene): Synthesis, Anion Binding, and Sensing of Anion Extraction Processes"],"prefix":"10.1002","volume":"45","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1502-3259","authenticated-orcid":false,"given":"Bhaskar","family":"Garg","sequence":"first","affiliation":[{"name":"Department of Chemistry IIT Roorkee  Roorkee 247667 India"},{"name":"Department of Chemistry School of Basic Sciences and Technology IIMT University  Meerut Uttar Pradesh 250001 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tanuja","family":"Bisht","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indira Priyadarshini Government Girls P. 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Taiwan"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2023,11,29]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja01561a054"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jeurceramsoc.2015.11.032"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40145-019-0335-3"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jeurceramsoc.2017.04.008"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/b909955g"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/pi.2527"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/pola.29478"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00289-019-02741-y"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jddst.2020.101879"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/jbm.b.34740"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099-0518(19990801)37:15<2933::AID-POLA26>3.0.CO;2-K"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/macp.200800235"},{"key":"e_1_2_6_11_3","doi-asserted-by":"publisher","DOI":"10.1021\/ja971373b"},{"key":"e_1_2_6_11_4","doi-asserted-by":"publisher","DOI":"10.1002\/pola.23950"},{"key":"e_1_2_6_11_5","doi-asserted-by":"publisher","DOI":"10.1021\/om049922r"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.polymer.2011.06.010"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00485A"},{"key":"e_1_2_6_12_3","doi-asserted-by":"publisher","DOI":"10.1021\/ma00073a021"},{"key":"e_1_2_6_12_4","doi-asserted-by":"publisher","DOI":"10.1023\/A:1021235922742"},{"key":"e_1_2_6_12_5","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-12-814213-4.00005-8"},{"key":"e_1_2_6_12_6","doi-asserted-by":"publisher","DOI":"10.1007\/978-1-4020-8172-9"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/om049166p"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma0347058"},{"key":"e_1_2_6_13_3","doi-asserted-by":"publisher","DOI":"10.1039\/B609412K"},{"key":"e_1_2_6_13_4","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2006.01.016"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0dt00105h"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.5b01820"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma201203w"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/marc.201200085"},{"key":"e_1_2_6_15_3","doi-asserted-by":"publisher","DOI":"10.1002\/marc.200900794"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm702299g"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1039\/b802623h"},{"key":"e_1_2_6_16_3","doi-asserted-by":"publisher","DOI":"10.1021\/ma702274c"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja301900s"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja960307r"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/a700685c"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201901424"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules21121653"},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10847-010-9849-6"}],"container-title":["Macromolecular 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