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In addition to its remarkable fluorescence behavior, TPA\u2010Peryl\u2010CMP shows promise as a sensor for Fe<jats:sup>3+<\/jats:sup> ions using a turn\u2010off strategy. Due to its exceptional stability and robust \u03c0\u2010electron system, this platform demonstrates remarkable sensitivity and selectivity, significantly improving detection capabilities for specific analytes. Detailed procedures related to the mechanism for detecting Fe<jats:sup>3+<\/jats:sup> ions are outlined for sensing Fe<jats:sup>3+<\/jats:sup> ions, revealing a notably strong linear correlation within the concentration range of 0\u20133\u00a0\u00b5<jats:sc>M<\/jats:sc>, with a correlation coefficient of 0.9936 and the Limit of detection (LOD) 20\u00a0nM. It is anticipated that development of such a kind of TPA\u2010Peryl\u2010CMP will observe broader applications in detecting various analytes related to environmental and biological systems.<\/jats:p>","DOI":"10.1002\/marc.202400263","type":"journal-article","created":{"date-parts":[[2024,6,15]],"date-time":"2024-06-15T15:23:30Z","timestamp":1718465010000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Selective and Sensitive Detection of Fe<sup>3+<\/sup> Ions Using a Red\u2010Emissive Fluorescent Probe Based on Triphenylamine and Perylene\u2010Linked Conjugated Microporous Polymer"],"prefix":"10.1002","volume":"45","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3111-6327","authenticated-orcid":false,"given":"Manivannan","family":"Madhu","sequence":"first","affiliation":[{"name":"Department of Chemistry National Sun Yat\u2010sen University  Kaohsiung 804 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