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Rapid Commun."],"published-print":{"date-parts":[[2024,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Electrochemistry has been widely used in energy storage, metallurgy, chemical synthesis and other fields since its birth using electricity as one of the cheapest reagents. However, compared with the revival of electrochemical synthesis of small molecules, the electrochemical polymerization for preparing macromolecules is still rudimentary due to formidable challenges. Herein, A unique electrochemical polymerization is disclosed between CS\n                    <jats:sub>2<\/jats:sub>\n                    and diamines at room temperature in an electrolyte\u2010free manner to access poly thioureas. Polythioureas have high selectivity for four metal ions, including Au\n                    <jats:sup>3+<\/jats:sup>\n                    , Ag\n                    <jats:sup>+<\/jats:sup>\n                    , Pt\n                    <jats:sup>4+<\/jats:sup>\n                    , and Hg\n                    <jats:sup>2+<\/jats:sup>\n                    , and can be used as an efficient adsorbent for recovering gold from metal waste.\n                  <\/jats:p>","DOI":"10.1002\/marc.202400491","type":"journal-article","created":{"date-parts":[[2024,9,5]],"date-time":"2024-09-05T06:39:06Z","timestamp":1725518346000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Electrochemical Polymerization to Access CS2\u2010Derived Polythioureas at Room Temperature"],"prefix":"10.1002","volume":"45","author":[{"given":"Changhui","family":"Su","sequence":"first","affiliation":[{"name":"Department of Polymer Science and Engineering School of Chemical Engineering Dalian University of Technology  Dalian 116024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuxin","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Polymer Science and Engineering School of Chemical Engineering Dalian University of Technology  Dalian 116024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8808-5154","authenticated-orcid":false,"given":"Nan","family":"Zheng","sequence":"additional","affiliation":[{"name":"Department of Polymer Science and Engineering School of Chemical Engineering Dalian University of Technology  Dalian 116024 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