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Rapid Commun."],"published-print":{"date-parts":[[2025,1]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Polymer gels are fascinating soft materials and have become excellent candidates for wearable electronics, biomedicine, sensors, etc. Synthetic gels usually suffer from poor mechanical properties, and integrating good mechanical properties, adhesiveness, stability, and self\u2010healing performances in one gel is more difficult. Herein, polymerization\u2010induced self\u2010assembly (PISA) providing PEG\u2010gels with an overall improvement in their comprehensive performances is reported. PISA synthesis is carried out in PEG (solvent) to efficiently produce various nanoparticles, which are used as the nanofillers in the subsequent synthesis of PEG\u2010gels with dynamic micelle\u2010crosslinked hierarchical structures. Compared to hydrogels, PEG\u2010gels show excellent long\u2010term stability due to the nonvolatile feature of PEG solvent. The hierarchical PEG\u2010gels (with nanofillers) exhibit better mechanical and adhesive properties than the homogeneous\u2010gels (without nanofillers). The energy dissipation mechanism of the PEG\u2010gels is analyzed via stress relaxation and cyclic mechanical tests. High\u2010density hydrogen bonds between the micelles and PAA matrix can be broken and reformed, endowing better self\u2010healing properties of the dynamic micelle\u2010crosslinked PEG gels. This work provides a simple strategy for producing hierarchical structural gels with enhanced properties, which offers fundamentals and inspirations for the designing of various advanced functional materials.<\/jats:p>","DOI":"10.1002\/marc.202400681","type":"journal-article","created":{"date-parts":[[2024,10,20]],"date-time":"2024-10-20T16:58:49Z","timestamp":1729443529000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Polymerization\u2010Induced Self\u2010Assembly Providing PEG\u2010Gels with Dynamic Micelle\u2010Crosslinked Hierarchical Structures and Overall Improvement of Their Comprehensive Performances"],"prefix":"10.1002","volume":"46","author":[{"given":"Zi\u2010Xuan","family":"Chang","sequence":"first","affiliation":[{"name":"Key Laboratory of Precision and Intelligent Chemistry Department of Polymer Science and Engineering University of Science and Technology of China  Hefei Anhui 230026 P. R. 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