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Rapid Commun."],"published-print":{"date-parts":[[2025,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>In polymer science, mechanochemistry is emerging as a powerful tool for materials science and molecular synthesis, offering novel avenues for controlled polymerization and post\u2010synthetic modification. Building upon the previous research, nitroxide\u2010mediated polymerization (NMP) is merged with mechanochemistry through the design of nitroxide\u2010based mechanophore macroinitiators, pioneering the first instance of a sonochemical nitroxide\u2010mediated\u2010type polymerization. As NMP usually requires high temperatures, this study demonstrates that a sonochemical NMP\u2010type process allows polymerization under reduced temperatures down to 55\u00a0\u00b0C. Moreover, depending on the nature of the employed monomers, gelated networks are obtained, demonstrating the adaptability of the mechanophore system. This study elucidates the potential of mechanochemistry in polymer synthesis, offering insights into manipulating polymerization kinetics and advancing materials science applications.<\/jats:p>","DOI":"10.1002\/marc.202400732","type":"journal-article","created":{"date-parts":[[2024,11,13]],"date-time":"2024-11-13T09:55:46Z","timestamp":1731491746000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Sonochemical Nitroxide\u2010Mediated Polymerization: Harnessing Sonochemistry for Polymer Synthesis"],"prefix":"10.1002","volume":"46","author":[{"given":"Christophe","family":"Pauly","sequence":"first","affiliation":[{"name":"Organic Chemistry Institute and Center for Soft Nanoscience University of M\u00fcnster  Corrensstra\u00dfe 40 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lisa","family":"Schlichter","sequence":"additional","affiliation":[{"name":"Organic Chemistry Institute and Center for Soft Nanoscience University of M\u00fcnster  Corrensstra\u00dfe 40 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bart Jan","family":"Ravoo","sequence":"additional","affiliation":[{"name":"Organic Chemistry Institute and Center for Soft Nanoscience University of M\u00fcnster  Corrensstra\u00dfe 40 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1706-513X","authenticated-orcid":false,"given":"Armido","family":"Studer","sequence":"additional","affiliation":[{"name":"Organic Chemistry Institute and Center for Soft Nanoscience University of M\u00fcnster  Corrensstra\u00dfe 40 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,13]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c09623"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs35526h"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201906755"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs60052a"},{"key":"e_1_2_7_5_1","first-page":"1159","volume":"67","author":"Staudinger H.","year":"1934","journal-title":"Eur. 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