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Rapid Commun."],"published-print":{"date-parts":[[2025,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The copolymerization of two or more monomers produces polymeric materials with unique properties that cannot be achieved with homopolymers. However, precise control over the polymer sequence remains challenging because the sequence is determined by the inherent reactivity of comonomers. Therefore, only limited methods using modified monomers or supramolecular interactions are reported. In this study, the sequence control of acrylate\u2010styrene copolymerization using multinuclear zinc complexes is reported. The copolymerization of the zinc acrylate complex with a polymeric sheet\u2010like structure and styrene in benzene affords a copolymer with a higher content of acrylate triad than calculated for the statistical random model, whereas tetranuclear zinc acrylate (TZA) affords a copolymer with fewer adjacent acrylate sequences. The copolymer with a higher content of acrylate triad exhibits a lower glass transition temperature because of the higher mobility of the longer polystyrene segments. These results highlight the promise of multinuclear zinc acrylate complexes as monomers for sequence\u2010controlled copolymerization.<\/jats:p>","DOI":"10.1002\/marc.202400742","type":"journal-article","created":{"date-parts":[[2024,11,9]],"date-time":"2024-11-09T13:44:33Z","timestamp":1731159873000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Sequence\u2010Controlled Copolymerization of Structurally Well\u2010Defined Multinuclear Zinc Acrylate Complexes and Styrene"],"prefix":"10.1002","volume":"46","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6663-3826","authenticated-orcid":false,"given":"Takanori","family":"Iwasaki","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biotechnology Graduate School of Engineering The University of Tokyo  7\u20103\u20101 Hongo Bunkyo\u2010ku Tokyo 113\u20138656 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