{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T16:00:44Z","timestamp":1792166444260,"version":"4.4.0"},"reference-count":43,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2024,12,27]],"date-time":"2024-12-27T00:00:00Z","timestamp":1735257600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22075108"],"award-info":[{"award-number":["22075108"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21905116"],"award-info":[{"award-number":["21905116"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100009555","name":"Henan Normal University","doi-asserted-by":"publisher","award":["2022B01"],"award-info":[{"award-number":["2022B01"]}],"id":[{"id":"10.13039\/100009555","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2025,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Diatomic catalysts enhance photocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction through synergistic effects. However, precisely regulating the distance between two catalytic centers to achieve synergistic catalysis poses significant challenges. In this study, a series of one\u2010dimensional (1D) covalent organic frameworks (COFs) are designed with adjustable micropores to facilitate efficient CO\n                    <jats:sub>2<\/jats:sub>\n                    photoreduction. CO\n                    <jats:sub>2<\/jats:sub>\n                    molecules are anchored between dual\u2010cobalt centers within micropores, thus effectively reducing their activation energy and initiating the photocatalytic process. Additionally, the formation of *COOH intermediates is significantly influenced by the coordination microenvironment around dual\u2010cobalt sites. Notably, COF\u2010Co\u2010N\n                    <jats:sub>4<\/jats:sub>\n                    exhibited remarkable CO\n                    <jats:sub>2<\/jats:sub>\n                    photoreduction activity with a CO evolution rate of 110.3 \u00b5mol\u00b7g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , which surpasses most of previously reported single\u2010atom\u2010site photocatalysts. Comprehensive characterization and density functional theory (DFT) calculations revealed that 1D COFs with dual\u2010cobalt sites possess the ability to anchor CO\n                    <jats:sub>2<\/jats:sub>\n                    molecules, thereby enhancing the efficacy of synergistic catalysis. Simultaneously, COF\u2010Co\u2010N\n                    <jats:sub>4<\/jats:sub>\n                    with quadruple nitrogen coordination significantly reduced the energy barrier of crucial *COOH intermediate, facilitating efficient photocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction. This study meticulously modulated the coordination microenvironment surrounding dual\u2010cobalt synergistic sites, providing new insight into the design of high\u2010performance photocatalysts.\n                  <\/jats:p>","DOI":"10.1002\/marc.202400780","type":"journal-article","created":{"date-parts":[[2024,12,28]],"date-time":"2024-12-28T02:29:31Z","timestamp":1735352971000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["1D Covalent Organic Frameworks with Tunable Dual\u2010Cobalt Synergistic Sites for Efficient CO\n                    <sub>2<\/sub>\n                    Photoreduction"],"prefix":"10.1002","volume":"46","author":[{"given":"Shu\u2010Kun","family":"Xia","sequence":"first","affiliation":[{"name":"Key Laboratory of Synthetic and Biological Colloids Ministry of Education School of Chemical and Material Engineering Jiangnan University  Wuxi 214122 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yong","family":"Liu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Synthetic and Biological Colloids Ministry of Education School of Chemical and Material Engineering Jiangnan University  Wuxi 214122 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruo\u2010Meng","family":"Zhu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Synthetic and Biological Colloids Ministry of Education School of Chemical and Material Engineering Jiangnan University  Wuxi 214122 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing\u2010Dong","family":"Feng","sequence":"additional","affiliation":[{"name":"Key Laboratory of Synthetic and Biological Colloids Ministry of Education School of Chemical and Material Engineering Jiangnan University  Wuxi 214122 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wang\u2010Kang","family":"Han","sequence":"additional","affiliation":[{"name":"Key Laboratory of Synthetic and Biological Colloids Ministry of Education School of Chemical and Material Engineering Jiangnan University  Wuxi 214122 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2227-8882","authenticated-orcid":false,"given":"Zhi\u2010Guo","family":"Gu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Synthetic and Biological Colloids Ministry of Education School of Chemical and Material Engineering Jiangnan University  Wuxi 214122 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,12,27]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1188566"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6EE00383D"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00163H"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2EE02449G"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00920E"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40843-023-2703-0"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2023.112876"},{"key":"e_1_2_8_8_1","volume":"451","author":"Lin S.","year":"2023","journal-title":"Science"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202303287"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b10380"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-021-00925-3"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2EE01037B"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202105135"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE02714J"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-15281-1"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.137802"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c00126"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202309820"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2024.124123"},{"key":"e_1_2_8_20_1","first-page":"1208","volume":"349","author":"Shi P.","year":"2023","journal-title":"Chem. 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