{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T19:30:15Z","timestamp":1791919815675,"version":"4.3.4"},"reference-count":28,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2024,12,27]],"date-time":"2024-12-27T00:00:00Z","timestamp":1735257600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2025,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The CO<jats:sub>2<\/jats:sub>\u2010epoxide addition to cyclic carbonate is of great significance but usually requires high temperatures and CO<jats:sub>2<\/jats:sub> pressures. Herein, a spirobifluorene\u2010based porous organic polymer catalyst is designed with a Co\u2010salen complex immobilized on the backbone (<jats:bold>ST\u2010CoSalen\u2010POP<\/jats:bold>) to enable CO<jats:sub>2<\/jats:sub> fixation under mild conditions. <jats:bold>ST\u2010CoSalen\u2010POP<\/jats:bold> possesses a high Co\u2010loading content (9.35 wt%), a large pore volume, and high CO<jats:sub>2<\/jats:sub> adsorption capacity. This catalyst achieves a 96% yield in the cycloaddition of CO<jats:sub>2<\/jats:sub> with epoxides at 25\u00a0\u00b0C and 0.1\u00a0MPa CO<jats:sub>2<\/jats:sub> pressures. Moreover, <jats:bold>ST\u2010CoSalen\u2010POP<\/jats:bold> also offers the advantages of wide adaptability over epoxide substrates and high structural stability for three consecutive cycles. This study presents a novel catalytic approach for promoting CO<jats:sub>2<\/jats:sub> fixation, offering a significant advancement in the efficient synthesis of fine chemicals.<\/jats:p>","DOI":"10.1002\/marc.202400836","type":"journal-article","created":{"date-parts":[[2024,12,27]],"date-time":"2024-12-27T08:35:06Z","timestamp":1735288506000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Building a Co\u2010Salen\u2010Immobilized Porous Organic Polymer Catalyst for CO<sub>2<\/sub> Cycloaddition"],"prefix":"10.1002","volume":"46","author":[{"given":"Shuai","family":"Gu","sequence":"first","affiliation":[{"name":"Hunan Key Laboratory of Micro &amp; Nano Materials Interface Science College of Chemistry and Chemical Engineering Central South University  Changsha 410083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Li","sequence":"additional","affiliation":[{"name":"Hunan Key Laboratory of Micro &amp; Nano Materials Interface Science College of Chemistry and Chemical Engineering Central South University  Changsha 410083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lingling","family":"Hu","sequence":"additional","affiliation":[{"name":"Hunan Key Laboratory of Micro &amp; Nano Materials Interface Science College of Chemistry and Chemical Engineering Central South University  Changsha 410083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuyu","family":"Guo","sequence":"additional","affiliation":[{"name":"Hunan Key Laboratory of Micro &amp; Nano Materials Interface Science College of Chemistry and Chemical Engineering Central South University  Changsha 410083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Feng","sequence":"additional","affiliation":[{"name":"Hunan Key Laboratory of Micro &amp; Nano Materials Interface Science College of Chemistry and Chemical Engineering Central South University  Changsha 410083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huicong","family":"Zhang","sequence":"additional","affiliation":[{"name":"Hunan Key Laboratory of Micro &amp; Nano Materials Interface Science College of Chemistry and Chemical Engineering Central South University  Changsha 410083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guipeng","family":"Yu","sequence":"additional","affiliation":[{"name":"Hunan Key Laboratory of Micro &amp; Nano Materials Interface Science College of Chemistry and Chemical Engineering Central South University  Changsha 410083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7398-3605","authenticated-orcid":false,"given":"Juntao","family":"Tang","sequence":"additional","affiliation":[{"name":"Hunan Key Laboratory of Micro &amp; Nano Materials Interface Science College of Chemistry and Chemical Engineering Central South University  Changsha 410083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,12,27]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja511329m"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/marc.201300741"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.3390\/pr8050548"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CC01401K"},{"key":"e_1_2_7_5_1","first-page":"24","volume":"14","author":"Ozcakir G.","year":"2023","journal-title":"Mater. 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