{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,8]],"date-time":"2026-07-08T00:44:31Z","timestamp":1783471471003,"version":"3.55.0"},"reference-count":52,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2024,12,20]],"date-time":"2024-12-20T00:00:00Z","timestamp":1734652800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2025,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The design of a new visible\u2010light methacrylated\u2010based kraft lignin photosensitizer (<jats:bold>MAcL<\/jats:bold>) of iodonium salt (Iod) for the free\u2010radical polymerization (FRP) of polyethylene glycol dimethacrylate (PEGDMA) under LEDs@405, 455, 470, 505, and 530 nm is reported. As demonstrated by laser flash photolysis (LFP) and electron paramagnetic resonance spin\u2010trapping (EPR ST) experiments, the combination of <jats:bold>MAcL<\/jats:bold> with an electron acceptor (Iod) and trimethylolpropane <jats:italic>tris<\/jats:italic>(3\u2010mercaptopropionate) (TT) used as a crosslinker, leads to the formation of highly efficient initiating radicals, i.e., thyil and carbon\u2010centred radicals, promoting thus the FRP of PEGDMA. The final methacrylate conversions of PEGDMA are very high and range from 80 to 95% under LED@530\u00a0nm and LED@405\u00a0nm, respectively. For the first time, <jats:bold>MAcL<\/jats:bold> is also used as a biocide agent as it produces singlet oxygen when exposed to visible light. The resulting photoinduced bio\u2010based materials incorporating <jats:bold>MAcL<\/jats:bold> demonstrate tremendous antibacterial properties against <jats:italic>Staphylococcus aureus<\/jats:italic> (<jats:italic>S. aureus<\/jats:italic>), inducing 100% bacterial death.<\/jats:p>","DOI":"10.1002\/marc.202400877","type":"journal-article","created":{"date-parts":[[2024,12,20]],"date-time":"2024-12-20T14:29:25Z","timestamp":1734704965000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Lignin Derivative as Visible\u2010Light Photo\u2010Initiating System for the Development of Biocide Materials under Light Irradiation"],"prefix":"10.1002","volume":"46","author":[{"given":"Christine","family":"Elian","sequence":"first","affiliation":[{"name":"Paris\u2010Est Creteil University CNRS ICMPE  UMR 7182 Thiais 94320 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fares","family":"Mouhoubi","sequence":"additional","affiliation":[{"name":"Paris\u2010Est Creteil University CNRS ICMPE  UMR 7182 Thiais 94320 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"R\u00e9gis","family":"Moilleron","sequence":"additional","affiliation":[{"name":"Paris\u2010Est Creteil University Laboratoire Eau Environnement Syst\u00e8mes Urbains (LEESU)  61 Avenue G\u00e9n\u00e9ral de Gaulle Cr\u00e9teil Cedex 94010 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Samir Abbad","family":"Andaloussi","sequence":"additional","affiliation":[{"name":"Paris\u2010Est Creteil University Laboratoire Eau Environnement Syst\u00e8mes Urbains (LEESU)  61 Avenue G\u00e9n\u00e9ral de Gaulle Cr\u00e9teil Cedex 94010 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Minh\u2010Huong","family":"Ha\u2010Thi","sequence":"additional","affiliation":[{"name":"Paris\u2010Saclay University CNRS Institut des Sciences Mol\u00e9culaires d'Orsay  Orsay 91405 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Annalisa","family":"Chiappone","sequence":"additional","affiliation":[{"name":"Dipartimento di Scienze Chimiche e Geologiche University\u00a0of Cagliari  Via Universit\u00e0 40 Cagliari 09124 Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrea","family":"Cosola","sequence":"additional","affiliation":[{"name":"Dipartimento Scienza Applicata e Tecnologia Politecnico di Torino  Corso Duca degli Abruzzi 24 Torino 10129 Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sonia","family":"Lajnef","sequence":"additional","affiliation":[{"name":"Paris Cit\u00e9 University CNRS Laboratoire de Chimie et Biochimie Pharmacologiques et Toxicologiques  Paris F\u201075006 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fabienne","family":"Peyrot","sequence":"additional","affiliation":[{"name":"Paris Cit\u00e9 University CNRS Laboratoire de Chimie et Biochimie Pharmacologiques et Toxicologiques  Paris F\u201075006 France"},{"name":"Sorbonne University Institut National Sup\u00e9rieur du Professorat et de l\u2019\u00c9ducation de l'acad\u00e9mie de Paris  Paris F\u201075016 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4272-5021","authenticated-orcid":false,"given":"Davy\u2010Louis","family":"Versace","sequence":"additional","affiliation":[{"name":"Paris\u2010Est Creteil University CNRS ICMPE  UMR 7182 Thiais 94320 France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,12,20]]},"reference":[{"key":"e_1_2_8_1_1","volume-title":"Exploring the science, technology and applications of U.V. and E.B. curing","author":"Davidson R. S.","year":"1999"},{"key":"e_1_2_8_2_1","volume-title":"Photogeneration of reactive species for UV curing","author":"Roffey C. G.","year":"1997"},{"key":"e_1_2_8_3_1","first-page":"1","volume-title":"In Electronic Applications","author":"Kloosterboer J. G.","year":"1988"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1146\/annurev.matsci.30.1.83"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/9783527648245"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2022.101517"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.9b02448"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202305963"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1PY00462J"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202405337"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.eurpolymj.2024.113121"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202400234"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0PY00551G"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1py00269d"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.eurpolymj.2020.110178"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-11522-0"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/cptc.202200091"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.3390\/catal13030493"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.eurpolymj.2023.111971"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9RA10212D"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3GC03551D"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0PY01768J"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3PY00681F"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5RA19499G"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10973-017-6094-x"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1080\/10601320500246974"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.7b03723"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsapm.1c01210"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1PY00126D"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.eurpolymj.2023.112369"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.8b13031"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/slct.201801039"},{"key":"e_1_2_8_33_1","volume":"8","author":"Zhang X.","year":"2020","journal-title":"ACS Sustainable Chem. Eng."},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2022.01.199"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.201802315"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201706564"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jmr.2005.08.013"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.3184\/030823408X310792"},{"key":"e_1_2_8_39_1","volume-title":"IR spectroscopy: an introduction","author":"G\u00fcnzler H.","year":"2002"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-94-011-6017-9"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1080\/15421406.2011.538611"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.8b05357"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/bk-1992-0531"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201601554"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20020104)8:1<102::AID-CHEM102>3.0.CO;2-S"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1038\/298545a0"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.5b02200"},{"key":"e_1_2_8_48_1","first-page":"701","author":"Forrester A. R.","year":"1971","journal-title":"J. Chem. Soc."},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.9b04686"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.9b01630"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.eurpolymj.2024.113291"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202407228"}],"container-title":["Macromolecular Rapid Communications"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.202400877","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,3,11]],"date-time":"2025-03-11T21:20:24Z","timestamp":1741728024000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/marc.202400877"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,12,20]]},"references-count":52,"journal-issue":{"issue":"5","published-print":{"date-parts":[[2025,3]]}},"alternative-id":["10.1002\/marc.202400877"],"URL":"https:\/\/doi.org\/10.1002\/marc.202400877","archive":["Portico"],"relation":{},"ISSN":["1022-1336","1521-3927"],"issn-type":[{"value":"1022-1336","type":"print"},{"value":"1521-3927","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,12,20]]},"assertion":[{"value":"2024-11-04","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-12-20","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2400877"}}