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Rapid Commun."],"published-print":{"date-parts":[[2025,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The development of high activity catalysts is crucial for improving industrial efficiency and mitigating environmental pollution. Polyisocyanides, with their pendant groups capable of forming ordered adjacent structures, offer a promising framework for designing cooperative catalysts that mimic the functionality of bimetallic centers. This unique structural arrangement is anticipated to significantly enhance catalytic activity in cooperative reactions. A novel approach to enhance the Suzuki coupling reaction using polymer\u2010supported catalysts is presented. In this study, stereoregular polyisocyanides with Salen\u2010Pd are functionalized to produce the Pd(II) metalized polyisocyanide (P1\u2010Pd). The rigid backbone of the polymer facilitates the parallel alignment of Salen\u2010Pd pendants, enabling double activation of the two substrates at an average distance of \u22481.2\u00a0nm. Catalytic efficiency is evaluated through Suzuki coupling reactions using various aryl halides. P1\u2010Pd demonstrates high activity, yielding the desired products with excellent conversion rates. Conversely, the irregular polymer counterpart P2\u2010Pd. P3\u2010Pd and the small molecule control C1\u2010Pd exhibit lower performance due to the absence of cooperative catalysis. To showcase the applicability of this strategy, Suzuki coupling is successfully conducted with outstanding yields for key drug intermediates, while also offering innovative insights for conjugated polymer synthesis.<\/jats:p>","DOI":"10.1002\/marc.202400899","type":"journal-article","created":{"date-parts":[[2024,12,23]],"date-time":"2024-12-23T13:44:32Z","timestamp":1734961472000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Salen\u2010Pd(II)\u2010Modified Stereoregular Polyisocyanides for Efficient Cooperative Catalysis of Suzuki Coupling Reaction"],"prefix":"10.1002","volume":"46","author":[{"given":"Bing\u2010Hao","family":"Liu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Supramolecular Structure and Materials College of Chemistry Jilin University  Changchun 130012 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yang","family":"Zong","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Supramolecular Structure and Materials College of Chemistry Jilin University  Changchun 130012 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Han\u2010Yi","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Supramolecular Structure and Materials College of Chemistry Jilin University  Changchun 130012 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Na","family":"Liu","sequence":"additional","affiliation":[{"name":"The School of Pharmaceutical Sciences Jilin University  1266 Fujin Road Changchun Jilin 130021 P. 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