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Compared with other symmetric FNFRAs, C6FT\u20102F2Cl features a shorter \u03c0\u2013\u03c0 stacking distance and an efficient zigzag charge transport channel, leading to enhanced and balanced charge carrier mobilities, lower non\u2010radiative energy loss and a higher short\u2010circuit current density. The power conversion efficiency (PCE) of the C6FT\u20102F2Cl\u2010based OSC reached 13.19%, which is among the best in FNFRA\u2010based devices. This work provides new valuable insights for the charge transport mechanism associated FNFRAs and paves a new route to the materials design toward high\u2010performance and low\u2010cost OSCs.\n                  <\/jats:p>","DOI":"10.1002\/marc.202401037","type":"journal-article","created":{"date-parts":[[2025,2,20]],"date-time":"2025-02-20T05:01:28Z","timestamp":1740027688000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Synergistic Molecular Engineering of Fully Non\u2010fused Ring Acceptors for Achieving Efficient Zigzag Charge Transport Channel and Low Non\u2010Radiative Voltage Loss"],"prefix":"10.1002","volume":"46","author":[{"given":"Xiao\u2010Peng","family":"Ru","sequence":"first","affiliation":[{"name":"State Key Laboratory of Applied Organic Chemistry (SKLAOC) Key Laboratory of Special Function Materials and Structure Design (MOE) College of Chemistry and Chemical Engineering Lanzhou University  Lanzhou 730000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhan","family":"Huang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Applied Organic Chemistry (SKLAOC) Key Laboratory of Special Function Materials and Structure Design (MOE) College of Chemistry and Chemical Engineering Lanzhou University  Lanzhou 730000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wen\u2010Jing","family":"Sun","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Applied Organic Chemistry (SKLAOC) Key Laboratory of Special Function Materials and Structure Design (MOE) College of Chemistry and Chemical Engineering Lanzhou University  Lanzhou 730000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sheng\u2010Min","family":"Gan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Applied Organic Chemistry (SKLAOC) Key Laboratory of Special Function Materials and Structure 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Key Laboratory of Special Function Materials and Structure Design (MOE) College of Chemistry and Chemical Engineering Lanzhou University  Lanzhou 730000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wen\u2010Cai","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Applied Organic Chemistry (SKLAOC) Key Laboratory of Special Function Materials and Structure Design (MOE) College of Chemistry and Chemical Engineering Lanzhou University  Lanzhou 730000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory and Institute of Elemento\u2010Organic Chemistry The Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials Renewable Energy Conversion and Storage Center (RECAST) College of Chemistry Nankai University  Tianjin 300071 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