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A microfluidic and ultrasonic field\u2010assisted solution processing strategy (FU) is employed to enhance the chain conformation order in the solution. By virtue of the UV\u2013vis absorption, X\u2010ray scattering, and X\u2010ray absorption spectroscopy, the FU\u2010processed P3HT solution with 1\u00a0wt.% doping level demonstrated the highest conformation order in terms of large chain conjugation length and optimal aggregate packing, which further dictating the highest mobility of the corresponding F4TCNQ\u2010doped P3HT film. The chain conjugation length is found to correlate more directly with OFET performance than the macroscopic crystallinity of the film and thus is proposed to be more intrinsic for understanding the electronic transport physics of conjugated polymers.<\/jats:p>","DOI":"10.1002\/marc.202401069","type":"journal-article","created":{"date-parts":[[2025,3,12]],"date-time":"2025-03-12T05:39:10Z","timestamp":1741757950000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Chain Conformational Ordering and Aggregation in Precursor Solution Affects the Charge Mobility of p\u2010Doped P3HT Films"],"prefix":"10.1002","volume":"46","author":[{"given":"Qing","family":"Zhang","sequence":"first","affiliation":[{"name":"National Synchrotron Radiation Laboratory University of Science and Technology of China  Hefei 230026 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