{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,10]],"date-time":"2026-10-10T19:34:29Z","timestamp":1791660869276,"version":"4.3.4"},"reference-count":51,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2025,2,9]],"date-time":"2025-02-09T00:00:00Z","timestamp":1739059200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2025,5]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The need for functional polymers derived from plant\u2010based materials has increased from a carbon\u2010neutral perspective. Herein, six different semialicyclic isosorbide\u2010containing diamine\u2010based polyimides (ISSD\u2010PIs) are synthesized by incorporating isosorbide (ISS), which is a D\u2010glucose derivative, into the diamine moiety to investigate the relationship between the chemical structure and optical, thermal, and dielectric properties. Compared with the conventional fully aromatic PIs, such as Kapton, the as\u2010prepared ISSD\u2010PIs demonstrate excellent optical transparency, low refractive indices (1.554\u20131.633), low birefringence (0.0084\u20130.0348) at 1310\u00a0nm, and low dielectric constants (2.93\u20133.36) with moderate dissipation factors (0.0112\u20130.0267) at 10\u00a0GHz. They also exhibit excellent thermal stability, with glass transition temperatures exceeding 250\u00a0\u00b0C and 5% thermal decomposition temperatures exceeding 400\u00a0\u00b0C. The chirality of the ISS skeleton remains intact, displaying characteristic circular dichroism. This study shows that the incorporation of ISS into PI chains enhances their optical and dielectric properties while maintaining thermal stability by increasing the free volume and reducing intermolecular interactions. In addition, the physical properties of the ISSD\u2010PIs are more dependent on the rigidity of the dianhydride moiety, which directly affects the molecular packing of the PI chains, rather than that of the diamine moiety.<\/jats:p>","DOI":"10.1002\/marc.202401113","type":"journal-article","created":{"date-parts":[[2025,2,10]],"date-time":"2025-02-10T20:10:52Z","timestamp":1739218252000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Optical, Dielectric, and Thermal Properties of Bio\u2010Based Polyimides Derived from An Isosorbide\u2010Containing Diamine"],"prefix":"10.1002","volume":"46","author":[{"given":"Yoshiyuki","family":"Tsurusaki","sequence":"first","affiliation":[{"name":"Department of Chemical Science and Engineering Institute of Science Tokyo  Ookayama 2\u201012\u20101\u2010E4\u20105 Meguro\u2010ku Tokyo 152\u20138552 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