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Whereas, it is still challenging to simultaneously gain mutually repulsive properties due to the existence of dissipation structure. Here, stretchable and recoverable double network (DN) hydrogels comprising highly entangled network structure and temperature\u2010induced dense hydrogen bond (HB)\u2010associated network structure are synthesized, in which slidable entanglements and dense HBs act as the effective crosslinking in first and second networks, respectively. Moveable entanglements and stable HB structures endow hydrogels with high stretchability (999%), high tensile strength (0.82\u00a0MPa) and high fracture toughness (4.51 MJ\u00b7m<jats:sup>\u22123<\/jats:sup>) through stress transmission along long chains and HB clusters energy dissipation. Moreover, the imposed energy on hydrogels can saved in oriented polymer chains by disentanglement as an entropy loss, thus ensuring the low hysteresis (6.2% at 100% tensile strain) of hydrogels. In addition, deformed hydrogel can be well remodeled and recovered (stress recovery of 95.5%) by temperature\u2013triggered sol\u2013gel transition of HB network. By means of entanglement and hydrogen bond strategies, stretchable DN hydrogels not only equilibrate the conflict of low hysteresis and high toughness, but also provides a new perspective to design high\u2010property hydrogels for cycle\u2010loaded applications.<\/jats:p>","DOI":"10.1002\/marc.202401134","type":"journal-article","created":{"date-parts":[[2025,2,17]],"date-time":"2025-02-17T15:44:37Z","timestamp":1739807077000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["A Facile Strategy to Construct Stretchable and Thermoreversible Double Network Hydrogels with Low Hysteresis and High Toughness Based on Entanglement and Hydrogen Bond Networks"],"prefix":"10.1002","volume":"46","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2314-7967","authenticated-orcid":false,"given":"Kun","family":"Lei","sequence":"first","affiliation":[{"name":"School of Medical Technology and Engineering Henan University of Science and Technology  263 Kaiyuan Road, Luolong Luoyang 471023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qixiu","family":"Jiang","sequence":"additional","affiliation":[{"name":"School of Medical Technology and Engineering Henan University of Science and Technology  263 Kaiyuan Road, Luolong Luoyang 471023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinling","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Shanghai Jiao Tong University  800 Dongchuan Road, Minhang Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dianhao","family":"Gong","sequence":"additional","affiliation":[{"name":"School of Medical Technology and Engineering Henan University of Science and Technology  263 Kaiyuan Road, Luolong Luoyang 471023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,2,17]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200304907"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.eurpolymj.2022.111347"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adf7075"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201504152"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202209913"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2019.12.026"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.isci.2021.103174"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202209606"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-17877-z"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/aisy.202200089"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2022.131434"},{"key":"e_1_2_8_12_1","volume":"32","author":"Li W. 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