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Rapid Commun."],"published-print":{"date-parts":[[2025,7]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>For the first time, thioketones, as effective (thio)carbonyl compounds as a monomer in Passerini multicomponent polymerizations, are demonstrated. The resulting polymer is imbued with functional thioesters directly in the backbone. Additionally, the ease in using thioketone monomers (as opposed to thioaldehyde\u2010based monomers) without the need for tedious workup and purification is highlighted. It is shown that soft matter materials made in this fashion can have their material properties easily tuned. Specifically, it is demonstrated that these polymers can be easily degraded via aminolysis, reduce their glass transition via dynamic trans\u2010thioesterification, or transformed into thermoset materials with the addition of thiols and maleimides via thiol\u2010ene chemistry.<\/jats:p>","DOI":"10.1002\/marc.202500076","type":"journal-article","created":{"date-parts":[[2025,5,19]],"date-time":"2025-05-19T04:03:31Z","timestamp":1747627411000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Thioketones as a Simple Route Toward Thioester\u2010Based Materials"],"prefix":"10.1002","volume":"46","author":[{"given":"Anne D.","family":"Fernando Pulle","sequence":"first","affiliation":[{"name":"School of Chemistry and Physics Queensland University of Technology  2 George Street Brisbane QLD 4000 Australia"},{"name":"Centre for Materials Science Queensland University of Technology  2 George Street Brisbane QLD 4000 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