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This approach significantly reduces the interfacial resistance and efficiently promote Li\u2010ion transport. This review aims to provide a comprehensive summary of the in situ polymerization processes, including free\u2010radical polymerization, ion\u2010initiated polymerization, as well as the materials involved, such as backbone materials, monomers, lithium salts, and initiators. Through this analysis, the review highlights how these processes can be optimized to improve the safety performance and achieve good interface stability between the PEs and electrodes. Additionally, this review evaluates the challenges and development trends of in situ polymerized electrolytes for high safety lithium batteries in the future.<\/jats:p>","DOI":"10.1002\/marc.202500306","type":"journal-article","created":{"date-parts":[[2025,7,13]],"date-time":"2025-07-13T12:40:01Z","timestamp":1752410401000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Recent Progress on In Situ Polymerized Electrolytes for Lithium\u2010Ion Batteries"],"prefix":"10.1002","volume":"46","author":[{"given":"Huihui","family":"Gan","sequence":"first","affiliation":[{"name":"Jiangxi Provincial Key Laboratory of Surface Engineering College of Materials and Energy Jiangxi Science and Technology Normal University  Nanchang P. R. 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