{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T03:07:57Z","timestamp":1789700877666,"version":"4.0.1"},"reference-count":40,"publisher":"Wiley","issue":"20","license":[{"start":{"date-parts":[[2025,7,30]],"date-time":"2025-07-30T00:00:00Z","timestamp":1753833600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"},{"start":{"date-parts":[[2025,7,30]],"date-time":"2025-07-30T00:00:00Z","timestamp":1753833600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR\u201022\u2010CPJ1\u20100077\u201001"],"award-info":[{"award-number":["ANR\u201022\u2010CPJ1\u20100077\u201001"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR\u201022\u2010CPJ1\u20100077\u201001"],"award-info":[{"award-number":["ANR\u201022\u2010CPJ1\u20100077\u201001"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR\u201022\u2010CPJ1\u20100077\u201001"],"award-info":[{"award-number":["ANR\u201022\u2010CPJ1\u20100077\u201001"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR\u201022\u2010CPJ1\u20100077\u201001"],"award-info":[{"award-number":["ANR\u201022\u2010CPJ1\u20100077\u201001"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR\u201022\u2010CPJ1\u20100077\u201001"],"award-info":[{"award-number":["ANR\u201022\u2010CPJ1\u20100077\u201001"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR\u201022\u2010CPJ1\u20100077\u201001"],"award-info":[{"award-number":["ANR\u201022\u2010CPJ1\u20100077\u201001"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2025,10]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>We report a catalyst\u2010free, one\u2010pot method for the upcycling of liquid polybutadiene that enables simultaneous backbone editing and introduction of sulfonamide and bromine functionalities under mild conditions. This sustainable alternative to metal\u2010catalyzed approaches, such as selenium\u2010based methods, offers access to functional polymers with tunable thermal and interfacial properties. The introduced bromine groups enable further orthogonal modifications, exemplified by efficient azidation. Remarkably, the resulting materials display previously unreported non\u2010conventional luminescence behavior, expanding the functional scope of upcycled commodity polymers and opening pathways toward applications in sensing, coatings, and bioimaging.<\/jats:p>","DOI":"10.1002\/marc.202500311","type":"journal-article","created":{"date-parts":[[2025,7,30]],"date-time":"2025-07-30T12:29:58Z","timestamp":1753878598000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Metal\u2010Free Multicomponent Upcycling of Polybutadiene to Sulfonamide\u2010Functionalized Materials"],"prefix":"10.1002","volume":"46","author":[{"given":"Janna","family":"Jeschke","sequence":"first","affiliation":[{"name":"Institut De Science des Mat\u00e9riaux de Mulhouse (IS2M) UMR 7361 Universit\u00e9 De Haute Alsace (UHA) 15 rue Jean Starcky Mulhouse France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jan","family":"Hobich","sequence":"additional","affiliation":[{"name":"Soft Matter Synthesis Laboratory Karlsruhe Institute of Technology (KIT) Hermann\u2010von\u2010Helmholtz\u2010Platz 1 Eggenstein\u2010Leopoldshafen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4683-0515","authenticated-orcid":false,"given":"Hatice","family":"Mutlu","sequence":"additional","affiliation":[{"name":"Institut De Science des Mat\u00e9riaux de Mulhouse (IS2M) UMR 7361 Universit\u00e9 De Haute Alsace (UHA) 15 rue Jean Starcky Mulhouse France"},{"name":"Department of Chemistry Technical Polymer Chemistry Rheinland\u2010Pf\u00e4lzische Technische Universit\u00e4t Kaiserslautern\u2010Landau (RPTU) Erwin\u2010Schr\u00f6dinger\u2010Stra\u00dfe, Geb\u00e4ude 52\u201354 Kaiserslautern Germany"},{"name":"Leibniz\u2010Institut F\u00fcr Verbundwerkstoffe GmbH Erwin\u2010Schr\u00f6dinger\u2010Stra\u00dfe 58 Geb\u00e4ude 58 \/ Raum 523 Kaiserslautern Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,7,30]]},"reference":[{"key":"e_1_2_7_2_1","unstructured":"European Environment Agency \u201cPlastics Overview \u201d accessed June 16 2024 https:\/\/www.eea.europa.eu\/en\/topics\/in\u2010depth\/plastics."},{"key":"e_1_2_7_3_1","unstructured":"R.Pravettoni \u201cGlobal Plastic Production and Future Trends until 2050 \u201d accessed June 26 2024 https:\/\/www.grida.no\/resources\/6923."},{"key":"e_1_2_7_4_1","unstructured":"Plastics Europe \u201cPlastics the Fast Facts \u2010 2023 \u201d accessed June 16 2024 https:\/\/plasticseurope.org\/knowledge\u2010hub\/plastics\u2010the\u2010fast\u2010facts\u20102023\/."},{"key":"e_1_2_7_5_1","unstructured":"C.Giacovelli \u201cSingle\u2010Use Plastics: a Roadmap for Sustainability United Nations Environment Programme \u201d accessed 16 June 2024 https:\/\/www.unep.org\/resources\/report\/single\u2010use\u2010plastics\u2010roadmap\u2010sustainability."},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.2172\/1616517"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c12730"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.7b00465"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7SC02574B"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b05799"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.0c00617"},{"key":"e_1_2_7_9_3","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00599"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC01425J"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC02861G"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202303115"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2PY20855E"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/pola.24231"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma202628p"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1PY01016F"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c07564"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.5b01453"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2019.07.003"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2024.116525"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.6b00679"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja104168q"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200801951"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/pola.26333"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/pola.26933"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar020230d"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym16121690"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.8b03872"},{"key":"e_1_2_7_29_1","unstructured":"Kuraray \u201cKuraray Liquid Rubber\u201d accessed June 26 2024 https:\/\/kuraray.com\/uploads\/5a8ac06d494af\/Kuraray_Liquid_Rubber.pdf."},{"key":"e_1_2_7_30_1","unstructured":"R. E.Smith \u201cCritical Surface Tension and Contact Angle with Water for Various Polymers \u201d July 9 2025 https:\/\/www.accudynetest.com\/polytable_03.html."},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1QM00808K"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jphotochemrev.2024.100653"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.9b01430"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2019.08.010"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.1c00311"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/marc.202170039"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/pol.20200432"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC05815E"}],"container-title":["Macromolecular Rapid Communications"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.202500311","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/marc.202500311","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.202500311","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,2,14]],"date-time":"2026-02-14T09:53:11Z","timestamp":1771062791000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/marc.202500311"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,7,30]]},"references-count":40,"journal-issue":{"issue":"20","published-print":{"date-parts":[[2025,10]]}},"alternative-id":["10.1002\/marc.202500311"],"URL":"https:\/\/doi.org\/10.1002\/marc.202500311","archive":["Portico"],"relation":{},"ISSN":["1022-1336","1521-3927"],"issn-type":[{"value":"1022-1336","type":"print"},{"value":"1521-3927","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,7,30]]},"assertion":[{"value":"2025-04-04","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-07-15","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-07-30","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e00311"}}