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Rapid Commun."],"published-print":{"date-parts":[[2025,9]]},"abstract":"<jats:title>ABSTRACT<\/jats:title><jats:p>We here describe a synthetic strategy to efficiently prepare polymer\u2010functionalized lanthanide\u2010doped nanoparticles (LNPs) via \u201cone\u2010pot\u201d <jats:italic>\u03c9<\/jats:italic>\u2010chain end aminolysis\/thiolate\u2010grafting of reversible addition\u2010fragmentation chain\u2010transfer (RAFT) polymers onto the surface of LNPs. Two representative polymers, poly(diethylene glycol methyl ether methacrylate) (PDEGMA) and poly[poly(ethylene glycol) methyl ether methacrylate] (PPEGMA), are prepared via RAFT, and their end\u2010group functionalization onto the surface of NaYF<jats:sub>4<\/jats:sub>:Yb, Tm\u2010based LNPs is demonstrated via an in situ tandem process. The achieved nanohybrids exhibit enhanced water\u2010dispersibility and cellular compatibility. Structural integrity and grafting confirmation of the constructed nanoconjugates are successfully made by combined studies of NMR, Fourier transform infrared (FTIR), fluorescence spectroscopy, and X\u2010ray diffraction (XRD). The size and morphology of the hybrid nanomaterials in solution are determined by dynamic light scattering (DLS) spectroscopy and high\u2010resolution transmission electron microscopy (HR\u2010TEM), and the photothermal activity is probed for their potential theranostic applications.<\/jats:p>","DOI":"10.1002\/marc.202500427","type":"journal-article","created":{"date-parts":[[2025,7,10]],"date-time":"2025-07-10T14:18:16Z","timestamp":1752157096000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["RAFT Polymers\u2010Capped Lanthanide\u2010Doped Nanoparticles via \u201cOne\u2010Pot\u201d Aminolysis\/Thiolate\u2010Grafting"],"prefix":"10.1002","volume":"46","author":[{"given":"Srideep","family":"Dasari","sequence":"first","affiliation":[{"name":"Department of Chemistry \u00c9cole Centrale School of Engineering Mahindra University Hyderabad 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