{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,9]],"date-time":"2026-03-09T17:12:15Z","timestamp":1773076335258,"version":"3.50.1"},"reference-count":66,"publisher":"Wiley","issue":"24","license":[{"start":{"date-parts":[[2025,8,17]],"date-time":"2025-08-17T00:00:00Z","timestamp":1755388800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2025,12]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Racemic octahedral metal complexes with \u0394\u00a0and\u00a0\u039b chirality and terminal C9 or C10 alkyl chains (\n                    <jats:bold>\n                      M\u2010C\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:bold>\n                    ,\n                    <jats:italic>n<\/jats:italic>\n                    = 9 or 10, M = Ru or Ir) are reported as the first octahedral metallomesogens that exhibit a micellar cubic (Cub\n                    <jats:sub>M<\/jats:sub>\n                    ) liquid\u2010crystal phase. The space group of the Cub\n                    <jats:sub>M<\/jats:sub>\n                    phase in\n                    <jats:italic>rac<\/jats:italic>\n                    \u2010\n                    <jats:bold>\n                      M\u2010C\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:bold>\n                    is , and each micelle comprises eight molecules in a J\u2010type aggregate structure. In contrast, enantiopure \u0394\u2010 and \u039b\u2010\n                    <jats:bold>\n                      M\u2010C\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:bold>\n                    exhibit a hexagonal\u2010columnar phase with helical stacking. To confirm that the \u0394\u2013\u039b chiral interaction acts as a driving force for the supramolecular assembly, quasi\u2010racemic mixtures of \u0394\u2010\n                    <jats:bold>Ru\u2010C9<\/jats:bold>\n                    and \u039b\u2010\n                    <jats:bold>Ir\u2010C9<\/jats:bold>\n                    as well as \u039b\u2010\n                    <jats:bold>Ru\u2010C9<\/jats:bold>\n                    and \u0394\u2010\n                    <jats:bold>Ir\u2010C9<\/jats:bold>\n                    were prepared in a 1:1 molar ratio. The quasi\u2010racemates exhibit a Cub\n                    <jats:sub>M<\/jats:sub>\n                    phase with a J\u2010type aggregate structure similar to that of pure\n                    <jats:italic>rac<\/jats:italic>\n                    \u2010\n                    <jats:bold>\n                      M\u2010C\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:bold>\n                    . They also exhibit novel vibrational circular dichroism signals that are not observed in the enantiopure compounds, which are attributed to the close \u0394 and \u039b packing. The obtained results suggest that mixing enantiomers in a quasi\u2010mirror image relationship could be a new approach for producing novel chiroptical materials.\n                  <\/jats:p>","DOI":"10.1002\/marc.202500485","type":"journal-article","created":{"date-parts":[[2025,8,18]],"date-time":"2025-08-18T03:34:05Z","timestamp":1755488045000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Optically Active Micellar\u2010Cubic Liquid Crystals from Quasi\u2010Racemic Octahedral Metallomesogens"],"prefix":"10.1002","volume":"46","author":[{"given":"Shiho","family":"Akiba","sequence":"first","affiliation":[{"name":"Department of Chemistry College of Humanities &amp; Sciences Nihon University  Setagaya\u2010ku Tokyo Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kozue","family":"Nishimoto","sequence":"additional","affiliation":[{"name":"Department of Chemistry School of Science Kitasato 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