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The P4VP block selectively interacts with phenol\u2010formaldehyde resol, enabling retention of microphase\u2010separated morphology during carbonization, while the fluorine\u2010containing PTFEMA block enhances phase separation through strong segmental repulsion. Ordered morphologies, including cylindrical structures, are formed upon blending with resol. These morphologies are preserved during thermal treatment at 900\u00b0C, leading to the formation of NMCs with well\u2010defined porous structures. The resulting NMCs exhibit tunable pore diameters ranging from 5.5 to 21.3\u00a0nm, controlled by the degree of polymerization of the PTFEMA block. These results highlight the potential of block copolymer design for achieving predictable mesopore architectures, offering a scalable platform for the development of functional porous materials.\n                  <\/jats:p>","DOI":"10.1002\/marc.202500529","type":"journal-article","created":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T10:52:21Z","timestamp":1759920741000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Fabrication of Nitrogen\u2010Doped Mesoporous Carbon With Tunable Pore Size via Self\u2010Assembly of Poly(4\u2010Vinylpyridine)\u2010\n                    <i>Block<\/i>\n                    \u2010Poly(2,2,2\u2010Trifluoroethyl Methacrylate)"],"prefix":"10.1002","volume":"46","author":[{"ORCID":"https:\/\/orcid.org\/0009-0002-2225-8822","authenticated-orcid":false,"given":"Youngwon","family":"Kong","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering 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